重金属离子铅, 镉, 铜在δ-MnO 2 上吸附及影响因素.docVIP

重金属离子铅、镉、铜在δ-MnO2上吸附及影响因素 朱丽珺1＊，张金池2，宰德欣1，王 忺2 1.南京林业大学理学院, 210037江苏南京;2.南京林业大学森林资源与环境学院, 210037江苏南京-mail: lxyzlj@njfu.edu.cn 水热法合成δ-MnO2并用X衍射光谱和傅立叶红外光谱进行表征，显示其结晶度差并表面含有一定的-OH基团。δ-MnO2对三个重金属离子Pb2+, Cd2+和Cu2+的吸附能力随着离子浓度的增加而增加。pH值增加对吸附有利。Pb2+在δ-MnO2上吸附用Freundlich、Langmuir和Temkin三个吸附等温式均可描述， Cd2+在δ-MnO2上的吸附用Langmuir吸附等温式、Cu2+在δ-MnO2上的吸附用Freundlich等温式拟合最合适。温度设置为298.15K、308.15K和323.15K时，δ-MnO2对三个重金属离子的吸附能力均随温度的增加而增加，吸附反应是吸热反应。 Tab.1Langmuir isotherm parameters 　 Temperature (K) Langmuir isotherm parameters （mmol·g-1） K R2 Pb2+ 298.15 1.614 79.45 0.9600 308.15 1.77 140.8 0.9522 323.15 1.855 299.4 0.9961 Cu2+ 298.15 1.484 51.82 0.9616 308.15 1.544 68.91 0.9696 323.15 1.626 70.95 0.9624 Cd2+ 298.15 0.7407 52.73 0.9728 308.15 0.8702 78.18 0.9813 323.15 0.9556 109.0 0.9808 Fig.1 X-ray diffraction pattern for δ – MnO2 关键词：δ-MnO2；b2+；d2+；u2+；附；响因素。 参考文献： [1]Han Runping, Lu Zhu, Zou Weihua, et al. Journal of Hazardous Materials, 2006, B137, 480–488 [2]Zhu Lijun, Zhang Jinchi, Zai Dexin, et al. Journal of Safety and Environment. 2007,7(4):20-23 Adsorption and affecting factors of Heavy Metal Ions Lead, cadmium and copper on δ –Manganese oxide Zhu Lijun1＊, Zhang Jinchi2, Zai Dexin1,Wang xian2 1.Nanjing Forest University Sciences College; 2.Nanjing Forest University Forest Resources and Environment College, 210037,Nanjing δ- MnO2 was prepared with hydrothermal treatment, and its crystalline structure was verified with X-ray diffraction spectroscopy. FTIR showed there were copious hydroxyl groups on the surface of δ- MnO2 for the adsorption. The adsorption capacity of three kinds of heavy metal ions Pb2+, Cd2+ and Cu2+ on the δ – MnO2 was all increased with the increase of ion concentration and the increase of pH. The adsorption isotherms of Pb2+ exhibited good correlation with Freundlich equations, Langmuir equations and Temkin equations, whereas equilibrium data of Cu2+ was best fitted to Freundl