英文文献-（VI）实验室对电镀含铬废水处理的吸附过程的可行性试验.docVIP

Ind. Eng. Chem. Res., 45 (14), 5059 -5065, 2006. 10.1021/ie060002d S0888-5885(06)00002-9 Web Release Date: June 6, 2006 Copyright ? 2006 American Chemical Society Biosorption Process for Treatment of Electroplating Wastewater Containing Cr(VI): Laboratory-Scale Feasibility Test Donghee Park, Yeoung-Sang Yun, Ji Hye Jo, and Jong Moon Park* Advanced Environmental Biotechnology Research Center, Department of Chemical Engineering, School of Environmental Science and Engineering, Pohang University of Science and Technology, San 31, Hyoja-dong, Pohang 790-784, South Korea, and Division of Environmental and Chemical Engineering, Research Institute of Industrial Technology, Chonbuk National University, 664-14ga, Duckjin-dong, Chonju 561-756, South Korea Received for review January 2, 2006 Revised manuscript received May 2, 2006 Accepted May 8, 2006 Abstract: Brown seaweed Ecklonia biomass was used for the treatment of electroplating wastewater that contains chromium and zinc ions. Batch experiments showed that Cr(VI) was removed from the wastewater through reduction to Cr(III) by contact with the biomass, whereas Cr(III) and Zn(II) were removed through adsorption to the binding sites of the biomass. Among various parameters, the solution pH most significantly affected the biosorptive capacity of the biomass. As the solution pH increased, the removal efficiency of Cr(VI) decreased, whereas that of Cr(III) and Zn(II) increased, for pH 5. This divergence of efficiency, because of the removal mechanisms of chromium and zinc ions, necessitated a two-stage biosorption process for the complete removal of both ions from the wastewater. The first stage comprises the removal of Cr(VI) by reduction into Cr(III) and of total chromium by partial adsorption at a low pH (1.5-2.5), and the second stage the removal of residual total chromium and Zn(II) by adsorption at elevated pH (4-5). A series of two columns that contain the Ecklonia biomass with a pH adjustment step between column