机械活化对碳化硅烧结性能影响毕业论文.docVIP

机械活化对碳化硅陶瓷烧结性能的影响 摘 要 首先机械活化的本质就是用机械力的方式向系统输入能量，改变系统的能量状态，而烧结的实质是为系统提供一个达到能量势垒的能量，从而使物理或者化学反应进行，最后达到小于初态能量的状态。其次将质量作用定律描述的物质加以概括，找到其本质特征，推广为数量作用规律。之后将这个能量与数量转换成对应的可以测量的量，建立机械活化对烧结过程的影响的动力学模型。在给定特殊值后用计算机进行数值模拟。模拟结果解释了一些烧结工艺的合理性。模拟结果预言了多孔陶瓷的制备新工艺。在此基础上进行实验验证。实验表明机械活化所影响的性能差异已观察到，并和预期模型相符，理论在对预言性方面，多孔陶瓷的现象也被观察到。由于很多测量量不能得到，因此本模拟过程的定性结论上是正确的。之后进行应用讨论在什么条件下可以采用机械活化的方式提高烧结性能的同时降低成本。最后对模型的不足之处进行说明。 关键词 机械活化，碳化硅，动力学，模型，烧结性能 ABSTRACT First, the nature of mechanical activation is inputting energy to change the systems energy state by using mechanical force. The essence of sintering is providing energy for a system so that the he system can reach the energy barrier . Then the physical or chemical reaction can start. The total energy of system will be less than the initial state energy state in the end. Secondly, finding essential feature of mater described by the mass action law, the law can be generalized to the law of quantity action. Measured amount can be used to match energy and the quantity. Dynamic model of the sintering process has been built ,what influences can be found after the mechanical activation. Sintering process has been simulated after special value was set. The simulation results explain the rationality of some of the sintering process. The simulation results predict that a new preparation process of porous ceramics. Experiment has been designed to prove the theory, then. The experiments show the differences affected by the mechanical activation. The results are agree with the model. Prediction as simulation results shown has been reality when the porous ceramics is achieved. The qualitative conclusions of this simulation is correct because of missing of the measured amount Then application performance is discussed on what conditions the mechanically activation can be used to improve the sintering performance while reducing costs Finally, the inadequacies of the model are described.. Key words: Mechanical activation, silicon carbide, dynamics model, sinte