微污染水源中溶解性有机氮组成规律及其水处理特性.pdfVIP

中国环境科学 2014,34(1) ：130~135 China Environmental Science 微污染水源中溶解性有机氮组成规律及其水处理特性 * 朱文倩,徐 斌 ,林 琳,陈英英,徐 倩 ( 同济大学,污染控制与资源化研究国家重点实验室,长江水环境教 部重点实验室,上海 200092) 摘要：以上海市黄浦江和青草沙长江原水为对象,研究了两大水源水中溶解性有机氮(DON)的含量变化、分子组成特征及其在常规净水工 艺中的去除效果,并对 DON 与常规水处理指标间的相关性进行了分析.结果表明:两种原水以 DOC 、DON 和 UV254 表征的有机物含量均以 小分子量(5kDa)和亲水性有机物为主;微污染黄浦江原水中同时存在外源性及内源性污染,而青草沙长江原水中内源性污染占主导地位; 饮用水常规净水处理工艺对黄浦江原水中DON 的去除率为40%,优于长江原水DON 的去除率16.7%;黄浦江和长江原水DON 浓度与DOC 和 UV254 相关性良好,其相关系数分别为 0.59,0.52 和 0.74,0.51;鉴于常规处理对 DON 去除效果有限,而 DON 是导致强三致特性含氮消毒副 产物(N-DBPs) 的总前体物,因此水厂应通过强化常规、深度处理等手段改善DON 在净水工艺中的去除效果. 关键词：微污染原水；溶解性有机氮；分子质量分布；亲疏水性；常规净水工艺；相关性 中图分类号： X131.2 文献标识码：A 文章编号：1000-6923(2014)01-0130-06 Studies on dissolved organic nitrogen compositions and water-treatment behavior in micro-polluted water. ZHU * Wen-qian, XU Bin , LIN Lin, CHEN Ying-ying, XU Qian (Key Laboratory of Yangtze Water Environment, Ministry of Education, State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China). China Environmental Science, 2014,34(1)：130~135 Abstract ：Dissolved organic nitrogen (DON) was the main precursors of toxic N-DBPs, and the removal effect of DON was unknown for conventional water treatment process (CWTP). Variation of existence and molecular composition of DON in Huangpu River and the Yangtze River and the removal effect in CWTP was investigated. The results showed that the small molecular ( 5kDa) and hydrophilic organic matters dominated the composition of DON, DOC and UV254 in both two kinds of raw water. In Huangpu River, both autochthonous and allochthonous NOM sources were found. However, the autochthonous sources dominated NOM sources in the Yangtze River. As the result of linear regression analysis of DON