顺丁烯二酸酐、醋酸乙烯酯、丙烯酰胺和甲基丙烯酸甲酯.docVIP

摘 要 以顺丁烯二酸酐、醋酸乙烯酯、丙烯酰胺和甲基丙烯酸甲酯为原料，过氧化苯甲酰为引发剂，采用本体聚合的方法合成了顺丁烯二酸酐-醋酸乙烯酯-丙烯酰胺-甲基丙烯酸甲酯共聚物，研究了引发剂用量、反应时间和反应温度对聚合物分子量的影响，并用红外光谱和热重分析仪对合成产物进行了测试表征。 实验结果表明： 1)顺丁烯二酸酐-醋酸乙烯酯-丙烯酰胺-甲基丙烯酸甲酯共聚物的重均分子量随引发剂用量的增加的变化趋势为：先升高，后降低，在0.35%处达到最高。 2)顺丁烯二酸酐-醋酸乙烯酯-丙烯酰胺-甲基丙烯酸甲酯共聚物的重均分子量随温度的升高的变化趋势为：先升高，后降低，在70℃处达到最高。 3）顺丁烯二酸酐-醋酸乙烯酯-丙烯酰胺-甲基丙烯酸甲酯共聚物的重均分子量随反应时间的延长的变化趋势为：先升高，后降低，在3h处达到最高。 4)顺丁烯二酸酐、醋酸乙烯酯、甲基丙烯酸甲酯和丙烯酰胺的摩尔比为0.9:1:0.9:1.5，反应温度70℃、引发剂用量为0.35%、反应时间3h，聚合物具有良好的水溶性，分子量为5.3497×105。 关键词：醋酸乙烯酯，顺丁烯二酸酐，丙烯酰胺,甲基丙烯酸甲酯,共聚 ABSTRACT The maleic anhydride - vinyl acetate - acrylamide - methyl methacrylate copolymer was synthetized by the method of bulk polymerization，using maleic anhydride, vinyl acetate, acrylamide and methyl methacrylate as raw materials, benzoyl peroxide as initiator. This thesis researched the influence of initiator concentration, reaction time and reaction temperature on the molecular weight, and the synthetic product was characterized by IR, TGA test characterization. The experimental results show that: 1)The weight average molecular mass of maleic anhydride - vinyl acetate - acrylamide - methyl methacrylate copolymer has a trend decrease after the first rise with the amount of initiator increasing and when the initiator is 0.35% ,the molecular mass is highest. 2)The weight average molecular mass of maleic anhydride - vinyl acetate - acrylamide - methyl methacrylate copolymer has a trend decrease after the first rise with the temperature increasing and when the temperature is 70 ℃,the molecular mass is highest. 3)The weight average molecular mass of maleic anhydride - vinyl acetate - acrylamide - methyl methacrylate copolymer has a trend decrease after the first rise with the reaction time increasing and when the reaction time is 3h ,the molecular mass is highest. 4)The property of the copolymer(maleic anhydride, vinyl acetate, methyl methacrylate and acrylamide)is preferable when the molar ratio is 0.9:1:0.9:1.5 , the reaction