大洋多金属结核与富钴结壳合并还原氨浸工艺的研究.docVIP

大洋多金属结核与富钴结壳合并还原氨浸工艺研究 王仍坚，蒋开喜，蒋训雄，汪胜东，范艳青，张登高 （北京矿冶研究总院，北京 100160） 摘要：以大洋多金属结核和富钴结壳按一定比例混合后的矿物为原料，在氨性体系中，以亚铜离子为催化剂，一氧化碳为还原剂，考察配矿比、硫酸铵浓度、氨浓度、亚铜离子浓度、温度等对有价金属浸出率的影响。结果表明，最佳浸出条件为：富钴结壳占比25%硫酸铵浓度25 g/L体系总氨120 g/L亚铜离子浓度10 g/L温度50 ℃一氧化碳量20 mL/min在上述最佳条件Ni、Co、Cu、Mn浸出率分别为97.15%、93.68%、92.64%、20.90%。实现了多金属结核和富钴结壳的合并冶炼，解决了单一富钴结壳氨浸法处理时钴浸出率低的难题。 关键词：大洋多金属结核富钴结壳；还原氨浸；硫酸铵中图分类号：TF8 文献标志码：A 文章编号：1007-7545（2014）09-0000-00 Study Merger Metallurgy Process of Ocean Polymetallic Nodules and Cobalt-rich Crusts WANG Reng-jian，JIANG Kai-xi，JIANG Xun-xiong，WANG Sheng-dong，FAN Yan-qing，ZHANG Deng-gao (Beijing General Research Institute of Mining Metallurgy, Beijing 100160, China) Abstract: Mineral mixed by ocean polymetallic nodules and cobalt-rich crusts was used as raw material. Effects of mixture ratio of ocean polymetallic nodules to cobalt-rich crusts, concentration of ammonium sulfate, ammonia concentration, cuprous ion concentration and temperature on leaching rate of valuable metals were investigated in low temperature ammonia solution system with cuprous ions as catalyst and carbon monoxide as reductant. The results show that leaching rates of nickel, cobalt, copper and manganese are 97.15%, 93.68%, 92.64% and 20.90% respectively under the optimum conditions including ratio of cobalt-rich crusts of 25%, concentration of ammonium sulfate of 25 g/L, ammonia concentration of 120 g/L, cuprous ion concentration of 10 g/L, temperature of 50 ℃, and flow rate of carbon monoxide of 20 mL/min. Combined metallurgy process of ocean polymetallic nodules and cobalt-rich crusts is achieved, and the problem of low cobalt leaching rate in leaching of single cobalt-rich crusts by ammonia is addressed. Key words：ocean polymetallic nodulescobalt-rich crusts; reduction ammonia leaching; ammonium sulfate 大洋多金属结核是一种含水率高（40%~50%）、有价金属品位低（（Ni+Co+Cu）≤3%）、多元素共生的复杂氧化矿[1]。北京矿冶研究总院亚铜离子氨浸工艺[]进行了详细研究，并形成了自主知识产权的自催化还原氨浸工艺[]，解决了钴回收率低和锰难回收的难题。 富钴结壳钴大于0.5%最高可达2%矿物组成特性与大洋多金属结核类似，赋存形态及化学成分富钴结壳含较高，较低。北京矿冶研究总院在常温常压下，利用