攀钢烧结烟气脱硫技术应用现状与发展.pdfVIP

攀钢烧结烟气脱硫技术应用现状与发展 ·1 · 攀钢烧结烟气脱硫技术应用现状与发展 邱正秋 黎建明 王建山 张小龙 （攀钢集团研究院有限公司，钒钛资源综合利用国家重点实验室，攀枝花 617000 ） 摘 要 简要叙述了攀钢烧结烟气的特点，介绍了有机胺（离子液）循环吸收法、氨-硫铵法、气固悬浮循环流化 床脱硫法 3 种脱硫工艺的原理、工艺流程及工程应用中存在的问题及工程应用效果，对比分析了三种方法的优缺点， 认为有机胺循环吸收法用于脱除高浓度的二氧化硫具有脱硫率高、不产生任何二次污染、同时可副产硫酸，符合攀 钢烧结烟气特性要求，并具有推广应用前景。 关键词 烧结烟气 氨硫铵法 石灰石脱硫 有机胺 脱硫 The Application and Development of Pangang Flue Gas Desulphurization Technology Qiu Zhengqiu Li Jianming Wang Jianshan Zhang Xiaolong (PanGang group Research Institute Co., Ltd., National Key Laboratory of Comprehensive Utilization of Vanadium Titanium Resource, Panzhihua, 617000) Abstract This paper summarized characteristics of Pangang sinstering gas, and introduced the theories, technological process and the existing problems and effect in project application of 3 kinds of desulfurization methods, including organic amine (ionic liquid) circulation absorption, ammonia-ammonium sulfate method and gas/solid suspension circulating fluidized bed. Advantages and disadvantages of these three methods were analyzed, and it was considered that organic amine circulation absorption was applied to absorb high concentration sulfur dioxide, with high desulfurization degree, byproduct sulfuric acid and no secondary pollution. This method met the requirement of Pangang sinstering gas, and showed the potentiality of wide applications. Key words sinstering gas, ammonia-ammonium sulfate, Limestone desulfurization, organic amine, desulfurization 1 引言 钢铁企业生产