矿山安全管理创新与实践.pdfVIP

40 3 Vol40, No3 20 10 6 BATT ERY BIMONT HLY Jun, 2010 P( MMAANST ) 李 根, 陈艳玲, 苗 琦 ( 中国地质大学材料科学与化学工程学院, 湖北武汉 430074) : 以甲基丙烯酸甲酯( MMA) 丙烯腈( AN) 和苯乙烯( ST) 的三元共聚物为基质, 采用相转化法制备P( MMAANST) 凝 胶聚合物电 质( GPE) 通过T G 和SEM 等方法, 对聚合物薄膜的稳定性和形貌进行分析, 结果表明: 薄膜具有良好的热 稳定性和丰富的孔隙结构; 用线性扫描伏安( LSV) 和交流阻抗( EIS) 测得: 在 25 时P ( MMAA NST) 的离子电导率为 263 mS/ cm, 电化学稳定窗口为50 V, 制备的模拟电池的循环性能稳定, 第30 次循环的比容量保持在最高值的95% 以上 : 相转换法; P( MMAANST) ; 凝胶聚合物电 质( GPE) : T M9129 : A : 100 1- 1579( 20 10) 03- 0131- 03 Preparing P( MMAANST) gel polymer electrolyte by phase inversion process LI G n, CHEN Yanling, MIAO Qi ( Faculty of Material Science and Chemistry Engineering, China University of Geosciences, Wuhan, H ubei 430074, China) Abstract: Using t rpolym r of m thyl m thacrylat ( MMA) , acrylonitril ( AN) and styr n ( ST) as th matrix , th P( MMAAN ST) g l polym r l ctrolyt ( GPE) was pr par d by phas inv rsion proc ssTh stability and morphology of t h polym r m mbran w r analyz d by T G and SEM m thods, th r sults show d that th m mbran had a high th rmal stability and good porosity By t sting at 25 wit h lin ar sw p voltamm try ( LSV) and l ctroch mical imp danc sp ctrum( EIS) , it w as found that th ionic conductivity of P( MMAA NST) was 263 mS/ cm, its l ctroch mical stability window was 50 V , th pr par d simulat ing c ll show d stabl cycl p rformanc , th sp cific capacity at th 30th cycl maintain d mor than 95% of th high st valu Key words:phas inv rsion proc ss; P ( MMAANST ) ; g l polym r l ctrolyt ( GPE) , 80 g 16 g [ 1] , , , ( , A R) 20 g [ 2 2 1 ( PEO) ( PMMA) MMA ( , AR) AN ( , AR) ST ( ,