锂电池的高温贮存的化学变化.pdfVIP

Journal of Power Sources 124 (2003) 124–132 Chemical transformation of the electrode surface of lithium-ion battery after storing at high temperature K. Araki, N. Sato∗ Tochigi RD Center, Honda RD Co. Ltd., Tochigi 321-3393, Japan Received 10 September 2002; received in revised form 14 January 2003; accepted 2 May 2003 Abstract The deterioration behavior of the Li-ion batteries consisted of LiMn1.7Al0.3O4 and hard carbon were investigated at the storage tempera- ture from 50 to 75 ◦C. The deterioration phenomena were analyzed by using XPS, FT-IR, SEM and TEM for the negative electrode surface. As a result, the negative electrode surface of deteriorated battery showed the dissociation of manganese from the positive active material, and also the decomposition of electrolyte and LiPF6 components was observed. When the storage temperature was over 65 ◦C, the ratio of PO4 3− component in the films particularly increased, suggesting that the transformation was thought to be caused by the decomposition of LiPF6 . Furthermore, we developed the solid electrolyte interface (SEI) observation technology. The film thickness of the deteriorated negative electrode was found to be varied from 40 to 200 nm. © 2003 Elsevier B.V. All rights reserved. Keywords: Lithium-ion battery; Battery deterioration; Chemical transformation; Surface analysis; Solid electrolyte interface; TEM image 1. Introduction reported the increase of dc impedance due to a swelling of separators in Li-ion batteries. After Li-ion batteries have been provided in the market In addition, Sloop et al.