气相色谱－质谱法研究的论文酸改性膨润土上松节油歧化反应.pdfVIP

气相色谱－质谱法研究酸改性膨润土上松节油歧化反应 梁杰珍，王琳琳，陈小鹏，穆允玲，陈毓静，梁佩华 (广西大学化学化工学院，广西南宁530004) 摘要：采用气相色谱-质谱联用技术(GC-MS)对酸改性膨润土催化剂上松节油催化歧化的反应产物进行了定性分 析，共分离出44个峰，鉴定出41种化合物，其中主要产物为对伞花烃和3-对孟烯，相对质量分数分别为56.57%和 10.46%；首次鉴定出松节油歧化产物中非挥发性物质和聚合物如西松烯的存在。对酸改性膨润土催化松节油的反 应过程进行了探讨，结果表明，双环单萜蒎烯的异构及分子间氢转移歧化反应为主反应，并伴随深度开环异构、 水合重排、聚合等副反应，倍半萜发生异构、脱氢及水合重排等反应；松节油主要成分蒎烯的转化率为100%， 对伞花烃收率为62.78% 。 关键词：酸改性膨润土；松节油；歧化；气相色谱-质谱联用 中图分类号：O629.6 文献标识码：A 文章编号： Study on disproportionation of turpentine over acid-modified bentonite by gas chromatography-mass spectrometry LIANG Jiezhen ，WANG Linlin ，CHEN Xiaopeng，CHEN Yujing，LIANG Peihua ( School of Chemistry and Chemical Engineering, Guang xi University, Nanning 530004, Guang xi, China ) Abstract ：The reaction products of products of turpentine disproportionation over acid-modified bentonite catalyst were analyzed and identified by chromatography and gas chromatography-mass spectrometry system (GC-MS). 44 peaks were separated and 41 compounds were tentatively identified. The main products were p -cymene and p -methane, which their relative contents were 56.57% and 10.46%, respectively. Some non-volatile products and polymeric species such as cembenen were frist identified in the products of turpentine disproportionation. In addition, the mechanism of turpentine disproportionation over acid-modified bentonite catalyst was preliminarily investigated based on the analysis results. The results showed that the isomerization and intermolecular hydrogen transfer dispro- portionation of bicyclic terpene pinene were main reaction. Simultaneously, some accompanying side reactions such as further ring-opening i