石墨烯应用于有机太阳能电池.pdfVIP

COMMUNICATION /JACS Luminscent Graphene Quantum Dots for Organic Photovoltaic Devices Vinay Gupta,* Neeraj Chaudhary, Ritu Srivastava, Gauri Datt Sharma, Ramil Bhardwaj, and Suresh Chand Organic and Hybrid Solar Cell Group, National Physical Laboratory, Dr. K. S. Krishnan Marg, New Delhi 110012, India S Supporting Information b ABSTRACT: Recent research in organic photovoltaic (OPV) is largely focused on developing low cost OPV materials such as graphene. However, graphene sheets (GSs) blended conjugated polymers are known to show inferior OPV characteristics as compared to fullerene adduct blended with conjugated polymer. Here, we demonstrate that graphene quantum dots blended with regioregular poly(3-hexylthiophene-2,5-diyl) or poly(2-methoxy-5-(2- ethylhexyloxy)-1,4phenylenevinylene) polymer results in a significant improvement in the OPV characteristics as compared to GSs blended conjugated polymers. This work has implications for inexpensive and efficient solar cells as well as organic light emitting diodes. The widespread commercialization of conjugated polymer- based organic photovoltaic (OPV) devices remains limited due to the use of high-cost donor and acceptor materials.1 Therefore, development of new cost-effective materials2 is critical for the future of OPVs. Quantum dots (QDs) (e.g., CdSe, Figure 1. (a) TEM image, (b) diameter distribution, and (c,d) FTIR CdTe, PbTe) are emerging as the leading acceptor materials in