低温化学法合成单晶氧化锌纳米带.pdfVIP

24 1 Vol.24 No.1 2 0 1 0 2 CHINESE JOURNAL OF MATERIALS RESEARCH February 2 0 1 0 ∗ ( 311258) 100 ZnO (Zn(OH) (CH COO) nH O) , ZnO (TEM) 2−x 3 x 2 (FESEM)X (XRD) (HRTEM) Æ (PL) ZnO , (HMT) ZnO , , , , TB321 1005-3093(2010)01-0097-06 Synthesis of Single Crystalline ZnO Nanobelts by the Solution Route DOU Qisheng∗∗ (School of Xiaoshan Science and Technology, Zhejiang Ocean University, Hangzhou 311258) * Supported by Scientific Research Fund of Zhejiang Provincial Education Department No.Y200908283. Manuscript received March 11, 2009; in revised form August 10, 2009 ** To whom correspondence should be addressed, Tel:(0571 E–mail:hxdqs@ ABSTRACT Single-crystalline ZnO nanobelts with non-layered structure were synthesized by the solu- tion route at 100 based on the transformation of the layered precursor (Zn(OH) (CH COO) nH O). 2−x 3 x 2 The morphology, structure and optical property of the ZnO nanobelts were characterized by transmission electron microscopy (TEM), field emission scanning electron microscopy (FESEM), X-ray powder diffrac- tion (XRD), high-resolution transmission electron microscopy (HRTEM) and photoluminescence (PL), respectively. It is indicated that the acetate anion and the weak organic alkali hexamethylenetetramine (HMT) play the critical role in the formation of the layered precursors at the beginning of the process. KEY WORDS inorganic non-metallic materials, ZnO, nanobelts, chemical solution approach, non- layered oxi