分光光度法测定高放废液中的铀张丽华.pdfVIP

CNIC-01879 IAE-0218 ( 中国原子能科学研究院, 北京, 102413) 样品用2. 0 mol/L HNO 调节酸度, 通过CL-TBP 萃淋树脂分 3 离柱(长为70 mm; 外 10 mm; 流速1.5~ 2. 0 mL/min), 用15 mL 1.0mol/L HNO3淋洗杂质, 再用15 mL 蒸馏水洗脱树脂上吸附的U [],分离纯化后的样品用分光光度法测定铀的含量采用0.05 偶氮胂为显色剂, 0.4 mol/L 氯乙酸-0.4 mol/L 氯乙酸钠为缓冲 剂,在 K= 652 nm 处测量吸光度模拟样品的相对标准偏差为 1.5 , 回收率为97 ~ 101 高放废液样品的RSD 为3 , 重加 回收率为102 : 123 Determination of Uranium in High-level Liqui Waste by Spectrophotometry ( I n Chinese) ZHANG Lihua LIU Huanliang SONG You (China Institute of Atomic Energy, Beijing, 102413) ABSTRACT A determination method of Uranium in highlevel liquid waste is described. The samples of HLLW are treated with nitric acid and passed through the ex- traction-chromatography column ( length: 70 mm, outer diamater: 10 mm, speed: 1. 5~ 2. 0 mL/min) . The interference elements are washed fully with 1.0 mol/L HNO solution, then Uranium absorbed on the resins is eluted with 3 distilled water. The Uranium is collected and determined by spectrophotome- try. In the case, arsenazoisused as developer, chloroacetic acid andits sod-i um salt are used as buffer agent. The relative standard deviation for synthetic sample is 1.5 and the recovery of uranium is 97 ~ 101 . The recovery for the samples from HLLW is 102 and RSD is 3 . Key wor s: Spectrophotometry, Uranium, High level liquid waste 124 ,, , 99 , ,, , , , ,U( )-ASA ( )U( )-CPA ()U( )- Br-PADAP-F ( 1) ( ) , ,, , Br-PADAP , , Br- PADAP ,, , 1 [ 1]