CdS量子点与CdSe量子点间荧光共振能量转移研究.pdfVIP

2010 年第68 卷 化 学 学 报 Vol. 68, 2010 第12 期, 1188～1192 ACTA CHIMICA SINICA No. 12, 1188～1192 ·研究论文· CdS 量子点与 CdSe 量子点间荧光共振能量转移研究 杨同辉 田宝丽 蒋晓红 李林松 杜祖亮* (河南大学特种功能材料教育部重点实验室 开封 475004) 摘要 在有机相中合成了不同尺寸的 CdS 和 CdSe 量子点, 并利用Langmuir-Blodgett (LB)技术将相同尺寸的 CdS 和 CdSe 量子点组装成多层复合纳米有序结构. 采用荧光光谱研究了CdS 和CdSe 量子点在混合体系和多层复合纳米有序 结构状态下的荧光共振能量转移(Fluorescence resonance energy transfer, FRET). 我们观察到CdS 和CdSe 量子点混合溶 液与当溶剂挥发形成固态膜中, CdS 量子点的荧光强度较溶液状态下强烈猝灭, 表明当颗粒间距离减小时CdS 和CdSe 量子点间产生较高效率的荧光共振能量转移. 在多层复合纳米有序结构中, 随着给体 CdS 量子点层数的增加, 单层受 体CdSe 量子点的荧光逐步增强, 这表明层间纵向能量转移率随给体层数的增加而提高. 关键词 CdS 量子点; CdSe 量子点; Langmuir-Blodgett (LB)技术; 荧光共振能量转移 Reaserch of Fluorescence Resonance Energy Transfer between CdS and CdSe Quantum Dots Yang, Tonghui Tian, Baoli Jiang, Xiaohong Li, Linsong Du, Zuliang* (Key Laboratory for Special Functional Materials of Ministry of Education, Henan University, Kaifeng 475004) Abstract It is synthesized that the CdS and CdSe quantum dots with the different sizes in the organic phase. The CdS and CdSe quantum dots were assembled into multi-layer composite nanostructures using LB technology. We also investigate the fluorescence resonance energy transfer (FRET) of the quantum dots system and the multi-layer nanostructures. The results reveal that the fluorescence intensity of CdS quantum dots comparatively weaken seriously with the complete volatilization of solvents in CdS and CdSe quantum dots hybrid solution. This results in the enhancing of the