铁氧体废料制备宽频高导锰锌铁氧体球磨工艺的研究.pdfVIP

E5 铁氧体废料制备宽频高导锰锌铁氧体球磨工艺研究 陈带军，彭长宏，朱云 （中南大学冶金科学与工程学院，湖南省长沙市 410083 ） 摘要：以低功耗锰锌铁氧体废料为原料，经湿法冶金和铁氧体工艺相结合的方法制备了宽频高导锰锌铁氧体。此过程中球磨 会影响粉料的化学组成和物理结构，进而影响烧结铁氧体样环的微观结构和磁性能。研究结果表明：用钢球球磨会引入较多 的 Si、Cr 杂质，实验采用普通铁球球磨；粉料粒径随着球磨时间的增加先减小而后趋于平稳；预烧粉粒径球磨到 1µm 时样 环内部气孔率小，密度大，组织结构均匀一致；此时样环初始磁导率最大可到 10000，频率到 150KHz 时初始磁导率不会减 小。 关键词：球磨；铁氧体废料；宽频；高导 Study of Milling process on the preparation of high peameability Mn-Zn ferrite with broad frequency characteristic from ferrite wastes CHEN Daijun, PENG Changhong, ZHU Yun ( School of Metallurgical Science and Engineering, Central South University, Changsha 410083) Abstract: High permeability ferrite with broad frequency characteristic was prepared by the hydrometallurgy and ceramic method, using the low power loss ferrite wastes as raw materials. In the process, milling could effect the powder chemical composition and physical structure, then effected the microstructure and the magnetic properties of the ferrite. The research result show that the impurities such as silicon and chromium will be brought in when we mill by steel ball, so we use iron ball to mill in the experiment. The powder particle size first decreases and then stabilized with the increase of milling time. The best particle size of the powder is about 1 um after milling, at this time the ferrite own small internal porosity, large density and uniform structure. The initial permeability of MnZn ferrite can reach 10000 and it can’t reduce when the frequency get 150KHz Key words: milling; ferrite wastes; broad frequency; high peameability 1 前言 锰锌铁氧体材料是现代电子工业及信息产业的基础功能材料，我国锰锌铁氧体的产量约为 20~30 万吨/年， [1] 占世界总产量的50%左右。在锰锌铁氧体产品的制备和加工过程中，会产生 10%~20%的废器件或抛光废料 。 目前仅以堆存处理，造成严重的环境污染和经济损失。实现锰锌铁氧体废料的资源化利用，具有重大的经济和 环境效益。随着化工、冶金、材料科学的交叉与融合，利用矿物原料或工业废渣直接制取铁氧体材料的研究取 得了重大进展[2-8] 。在前人工作的基础上，