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Harmonising Rock Engineering and the Environment – Qian Zhou (eds)
© 2012 Taylor Francis Group, London, ISBN 978-0-415-80444-8
The effect of certain chemical solutions on some material
properties of clay bearing rocks
P. Hagan, S. Saydam, E. Elias, L. Deramore Denver B. Hebblewhite
School of Mining Engineering, The University of New South Wales, Sydney, Australia
ABSTRACT: The addition of water to rock is known to change its material properties. These changes can be both beneficial
as well as detrimental in terms of rock strength, stability of rock excavations and the process of mechanical rock excavation.
This paper presents the results of a study to exam what effect certain chemical solutions have in ameliorating the changes in
material properties brought about after clay bearing rock is exposed to water.
Two rock samples were used in the study sourced from coal mines in eastern Australia. The clay mineral in each sample was
determined to be nacrite. The chemical solutions used in this study included potassium chloride and copper sulphate. A range
of material property tests was undertaken including strength, hardness, weatherability and machine cuttability to assess any
difference between rock immersed in water and in the chemical solutions.
The study confirmed earlier findings of a decrease in rock strength and cutting properties after immersion of clay bearing
rock in water. Immersion in the chemical solution however was found to neutralise the deterioration in property values achieving
similar levels to that attained with dry untreated rock samples. The results also suggest there is a time dependency factor in
the reaction between rock and chemical solution as the results differed wit
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