MPS_SiO_2_PS核壳型复合粒子的形态与玻璃化转变温度研究_刘兵.pdfVIP

36 12 V ol. 36 N o. 12 2007 12 A pplied Chem ica l Indu stry D ec. 2007 MPS-SiO /PS 2 刘兵, 史铁钧, 郑玉艳 , 230009) : , pH , - SiO2 , 3- ) M PS) , M PS-SiO2 M PS-S iO2 , , M PS-S iO 2 / PS, M PS-S iO2 200 nm , ; M PS-SiO 80 nm , M PS-S iO 2 2 M PS-SiO2 /PS Tg ) , M P S-S iO2 , Tg ; M PS-S iO2 , Tg : ; ; -; : O 631 : A : 1671- 3206 2007) 12- 1171- 05 Study on morphology and glass transition temperature ofMPS-SiO /PS core-shell composite particles 2 L I U B ing, SH I T ie-j un, ZH EN G Yu-yan Schoo l of Chem ical Eng inee ring, H efe iU n iversity o f T echno logy, H efe i 230009, Ch ina) Abstract: M onod ispersed S iO2 spherica l part ic les prepared by hydro lysis of tetraethoxy silane v ia so l-ge l m ethod under alkalescen t condition. M PS-S iO2 w ere gained through the m onod ispersed S iO2 m od ified by 3- trmi ethoxysilyl) propy l m ethacrylate MPS ). M PS-S iO2 /PS co re-shell com posite partic les w ere pre- pared by emu lsion po lym erization. T he MPS-S iO w ere em ployed as seeds and the styrene as the m onom er 2 of she