空心玻璃微球表面接枝聚苯乙烯及其性能研究.pdfVIP

17 6 Vo l1 17 N o16 2 0 0 9 12 MATER IALS SCIENCE TECHNOLOGY Dec. , 2009 1 1 2 2 1 潘顺龙, 张敬杰 , 邓建国, 贺传兰 , 宋广智 ( 1. , 100080, E m ail: psl7699@ yahoo. com. cn; 2. , 621900) : 空心玻璃微球表面改性有利于改善其与基体间的相容性, 提高复合泡沫性能. 通过 枝聚苯乙烯对 空心玻璃微球进行表面处理, 采用 SEMIR热失重等方法分析了反应条件对 枝的影响. 结果表明, 枝反 应过程中提高反应温度延长反应时间有利于 枝率的提高, 但温度过高会加速单体自聚, 降低 枝率. 枝 处理后, 随着聚合物层的增厚, 空心玻璃微球表面缺陷减小, 破损率降低, 抗压强度得到 一定程度提高. : 空心玻璃微球; 表面 枝; 抗压强度 : TB332 : A : 1005 0299( 2009) 06 0844 04 Surface m odification of hollow glass m icrospheres w ith grafting polysty rene and its prop erties 1 1 2 2 1 PAN Shun long , ZHANG Jing jie, DENG Jian guo, HE Chuan lan , SONG Guang zhi ( 1. Techn ical Institute of Physics and Chem istry, ChineseA cademy of Science, Beijing 100080, Ch ina, E m ail: psl7699@ yahoo. com. cn; 2. Institute of Chem icalM aterials, Ch ina Academy of Engineering Physics, M ianyang 621900, Ch ina) Abs tract: To mi prove the properties of syntactic foams, the surface of hollow glassm icrosphereswasmodified by grafting polystyrene in this study. The influence of temperature and tmi e on the reaction was studied by SEM, IR and TG. Results show that the grafting rate is promotedw ith the increased reaction temperature and the prolonged reaction tmi e. But, the overhigh temperature w ill result in the decrease of grafting rate. The crush strength of themodified surface ofm icrospheres is enhanced to a certain extentw ith the increase of graft ing rate. K ey w ord s: hollow glassm