淮南朱集井田岩浆侵入区煤中稀土元素的地球化学特征.pdfVIP

淮南朱集井田岩浆侵入区煤中稀土元素 的地球化学特征 1 1 2 黄 晖, 韩必武, 程世东 1. 淮南矿业集团有限公司安全开采总院地质院，安徽 淮南 232000 2. 淮南矿业集团有限公司朱集东煤矿，安徽 淮南 232000 摘 要：本研究采用电感耦合等离子体-光学发射光谱仪（ICP-AES ），系统测定了淮南煤田朱集井田补勘 阶段29 个钻孔中197 个煤样品的稀土元素含量。通过对煤中稀土元素地球化学参数分析，本研究得出以下 认识：以储量为加权因子，对比研究了岩浆侵入煤层与正常煤层中稀土元素含量和地球化学参数特征，得 出岩浆岩或者岩浆热液中的稀土元素的含量与受岩浆影响的煤中稀土元素的含量并无直接关系；10 个煤层 的稀土元素的球粒陨石标准化曲线特征基本一致，呈窄振幅的Ce/Ce*值和Eu/Eu* 中度亏损（0.49-0.70 ）的 特点，这说明泥炭沼泽沉积演化和区域断层对煤中稀土元素含量和分布模式的影响较小。 关 键 词：稀土元素；煤；岩浆侵入；朱集井田；淮南煤田 中图分类号：P 618. 7; P 618. 11 文献标志码：A 文章编号： doi: Characteristics of REEs in Coals from the Igneous Intrusion Area of the Zhuji Coal Mine, Anhui 1 1 2 HUANG Hui ，HAN Bi-wu ，CHENG Shi-dong 1. Safe mining and geology institute, Huainan mining group co., LTD, Huainan, Anhui 232000, China ； 2. Zhuj coal mine，Huainan mining group co., LTD, Huainan, Anhui 232000, China Abstract ：The contents of rare earth elements (REEs) of 197 coal samples from 29 boreholes in the Zhuji coal mine, Huainan Coalfield, Anhui Province, China, were determined by the high-precision ICP-AES and the geochemical characteristics of REEs in coals were discussed. On the basis of the reserve-weighted average content and analyzing the spatial (different locations of boreholes) and temporal (different depositional eras of coal seams) variations of REEs geochemistry, this study found that the contents of REEs in the magmatic rocks and in the magmatic hydrothermal have no direct relationship with the contents of REEs in igneous intruded coal. The chondrite standardized curve characteristics of 10 coal seam REEs were similar, a Ce/Ce* values were in a narro