Na-Al改性膨润土氨氮吸附材料的制备研究.pdfVIP

第 卷第 期 38 2 Vol.38 No.2 非金属矿 2015 年3月  Non-Metallic Mines March, 2015 Na-Al改性膨润土氨氮吸附材料的制备研究 1 2 1 1 王高锋  屈小梭  孙志明  郑水林 （1 中国矿业大学 （北京）化学与环境工程学院，北京 100083 ；2 中华环保联合会环保技术标准研究专业委员会，北京 100012） 摘  要 采用部分钠化- 铝化的方法对膨润土改性制备氨氮吸附材料，研究改性剂钠铝比、改性剂用量、改性时间等制备条件对改性膨润土 氨氮吸附性能的影响，探究改性膨润土吸附氨氮机理。试验结果表明：优化改性条件为改性剂钠铝比5 ∶1，改性剂用量6%，改性时间2 h ；对低浓 度模拟氨氮废水，改性后膨润土矿物材料吸附氨氮量明显高于改性前原矿，制得的吸附材料对初始质量浓度为5 mg/L、100 mL 实验室模拟氨氮废 水的氨氮去除率达到79.03%；氨氮吸附方式为阳离子交换吸附，通过Na-Al 改性提高了膨润土材料的阳离子交换容量，从而提高了膨润土吸附性 能。 关键词 膨润土；改性；吸附；氨氮废水 TQ424.2;X703 A 1000-8098(2015)02-0068-03 中图分类号： 文献标识码： 文章编号： Research on Preparation of Ammonia Nitrogen Adsorbent of Na-Al Modifying Bentonite Wang Gaofeng1 Qu Xiaosuo2 Sun Zhiming1 Zheng Shuilin1 (1 School of Chemical and Environment Engineering, Chinese University of Mining and Technology(Beijing), Beijing 100083; 2 Technology and Standard of Environmental Protection Research Professional Committee of All China Environment Federation, Beijing 100012) Abstract A kind of ammonia nitrogen adsorbent was prepared through part of Na-Al modify technique. The effect of the ratio of sodium chloride and aluminum chloride, the amount of modifier and the modification time on the ammonium nitrogen adsorption property were studied. Moreover, the modification mechanism of ammonia nitrogen adsorbent was researched. It is observed that the optimized conditions are the ratio of sodium chloride and aluminum chloride is 5 1, the amount of modifier is 6% ,the modification time