AZ31镁合金表面聚吡咯的化学氧化合成及其对镁合金的耐蚀性能.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) Month Acta Phys. -Chim. Sin., 2011, 27(X): 01-09 01 [Article] AZ31 镁合金表面聚吡咯的化学氧化合成及其对镁合金的耐蚀性能 黄 荣 陈明安* 路学斌 ( 中南大学材料科学与工程学院, 长沙410083) 摘要： 以对甲苯磺酸钠为掺杂剂, 三氯化铁为氧化剂, 在AZ31 镁合金表面化学氧化聚合制备聚吡咯(PPy)膜. 采用傅里叶变换红外(FTIR)光谱分析了镁合金表面聚吡咯膜结构, 通过电化学极化曲线、交流阻抗测试研究了 其耐蚀性能, 通过扫描电子显微镜(SEM)、X 射线能量散射谱(EDS)分析了表面形貌和成分. 和镁合金裸样相 比, 聚吡咯膜对镁合金腐蚀有一定的抑制作用. 硅烷预处理改善了镁合金/聚吡咯体系的耐腐蚀性能, 使腐蚀电 位正移了110 mV, 电流密度减小了约2 个数量级. 关键词： 聚吡咯; AZ31 镁合金; 硅烷; 耐蚀性 中图分类号： O647 Chemical Oxidative Polymerization of Polypyrrole and Its Corrosion Resistance on the AZ31 Magnesium Alloy HUANG Rong CHEN Ming-An* LU Xue-Bin (School of Materials Science and Engineering, Central South University, Changsha 410083, P. R. China) Abstract ： Polypyrrole (PPy) was chemically synthesized from pyrrole using sodium p-toluenesulfonate as a doping agent and ferric chloride as an oxidant on the surface of the AZ31 magnesium alloy. Fourier transform infrared (FTIR) spectroscopy was used for structural characterization of the PPy film. The corrosion behavior of the PPy coated AZ31 Mg alloy was studied using an electrochemical polarization test and electrochemical impedance spectroscopy. Scanning electron microscope (SEM) and energy dispersive X-ray analysis (EDS) were used to observe the surface morphology and for elemental analysis of the film, respectively. The PPy film showed a certain corrosion inhibition on the AZ31 magnesium alloy. Silane pretreatment can improve the corrosion protectio