高效湿处理的WOLED.pptVIP

Outline 概述 实验 结果讨论 总结 全色显示 固体照明光源 液晶显示的背光源 WOLED 高的发光效率； 高的显色指数； 较高的寿命； 绿色、面光源、无辐射 电子的能量状态 单重态S表示所有电子都是自旋配对的（大多数基态分子都处于单重态） 三重态 T表示电子在跃迁过程中伴随着自旋方向的变化（自旋平行） 激发分子从第一激发单重态的最低振动能级跃迁到基态各振动能级时所产生的光子辐射称为荧光。 激发分子由第一激发三重态的最低振动能级跃迁到基态各振动能级时所产生的光子辐射称为磷光。 基态 单重态S 三重态T E 其中S0、S1和S2分别表示分子的基态、第一和第二电子激发的单重态 T1和T2则分别表示分子的第一和第二电子激发的三重态。 V=0、1、2、3、…表示基态和激发态的振动能级。 S2 S1 S0 T1 吸 收 发 射 荧 光 发 射 磷 光 系间跨越 内转换 振动弛豫 能 量 l 2 l 1 l 3 外转换 l ?2 T2 内转换 振动弛豫 The blue-emitting component used in a WOLED comes through from fluorescent DPVBi(4,40-bis(2,2-diphenylethenyl)biphenyl),Sprio-fluorenes,Super p-conjugating molecules like anthracene and perylene, carbazole or triphenylamine modified molecules, transition metal co-mplexes to phosphorescent fluorine substituted iridium complexes, e.g. FIrpic,iridium(III) bis[(4,6-difluorophenyl)-pyridinato-N,C2′]picolinate.In all these reports, the blue emitting material is completely different from the green, yellow or red color emitting materials in both chemical structure and physical property. In this paper, we use the ligand as the blue emitter and the corresponding iridium complex as the yellow emitter to produce white color. reduce the cost of synthesis the energy transfer from ligand to complex is efficient the homogeneity may be improved device efficiency and stability 实验 Scheme 1. The ligands were labeled as L–H, L–CH3, L–Ph and L–F, respectively, the complexes were labeled as Ir–H, Ir–CH3, Ir–Ph and Ir–F, respectively Carbazole para-bromated benzene derivatives 2,5-dibromopyridine For the ligands we expect to get deep-blue emission and for the complexes we expect to red-shift the usually green-emitting phosphorescence. OLED器件结构 The devices were measured with a current/voltage source/measure unit (Keithley 2400) and a PR-650 luminance color meter. The color meter was placed on the bottom of the test device to mea ure the front luminance. 玻璃基片分别放入盛有清洗液、去离子水、丙酮以及异丙酮的容器中进行超声清洗处理。接着, 放在紫外臭氧室10分钟。 high vacuum 10-4mbar 结果讨论