碳包覆金属纳米粒子.ppt

Carbonization Our Group Highlights A simple technique for preparation of carbon encapsulated magnetic metal nanoparticles by one-step heating the mixture of organic compounds and Fe, Co, Ni nitrate! Illustrations Self-propagation combustion synthesis Advantage of the method Energy conservation, low pollution, low cost, high efficiency Feasibility Difference in chemical reactivity between carbon and metal Present product Onion carbon, CNTs, core-shell? Prospective An efficient approach to production of core-shell structure materials. Self-propagation combustion synthesis Instrumental methods X-ray diffraction Phase characterization, crystallite size, graphitization degree (High resolution) transmission electron microscopy Morphology, relationship between core-crystal orientation and graphitic shell growth, size distribution Raman spectroscopy Electron interaction, amorphous carbon detection X-ray photoelectron spectroscopy Valence distribution of the core element, electron interaction Infrared spectroscopy Organic functional groups? Surface edge? X-ray diffraction Phase characterization Assistant tools: ICDD-JCPDF cards Crystallite size Scherrer formula: d = 0.89 λ / B cosθ Graphitization degree Calculation formula Z. F. Qian, et al. Carbon techniques [M]. Pekin: Metallurgy Industry Press, 2000: 218-9. (High Resolution) transmission electron microscopy Morphology Influence of Core-crystal orientation on Shells growth Prospective? Role of core? Core Crystal plane, the density of shells (High Resolution) transmission electron microscopy Raman spectroscopy Surface charge coordination of the core? Core radius Vs G band upshift? Potential application Modern electronics and electrical engineering Data storage High dispersed, avoid coupling Magnetic ink Xerography Magnetic fluid Tribology Potential application Tribology Role of the shells high strength, ball bearing, lubricant Role