热喷涂LDPEn-SiO2复合涂层非等温结晶动力学.pdf

No．3 第62卷第3期 化工学报 V01．62 2011 CIESC March 2011年3月 Journal 热喷涂LDPE／n—Si02复合涂层非等温 结晶动力学 李亚东，朱忠诚，张晓静，何领好，张忠厚 (郑州轻工业学院，河南省表界面科学霞点实验室，河南郑州450002) 示扫描量热法(DSC)对涂层的非等温结晶行为进行研究，并用Jeziorny法和Mo法进行处理。结果表明， 却速率的增加而增加。且n-SiO。的加入使复合涂层的结晶速率常数和Avrami指数略有升高、半结晶时间降低， 结晶速率增大，表明n-SiO。起到了成核剂作用。 关键词：热喷涂；低密度聚乙烯；纳米氧化硅；非等温结晶动力学；复合涂层 332 文献标志码：A 中图分类号：TB of Non—isothermal kinetics crystallizationthermallysprayed compositecoating low—densitypolyethylene／nano-Si02 LI Yadong。ZHUZhongcheng，ZHANGXiaojing，HELinghao，ZHANGZhonghou Institute Provincial (ZhengzhouofLightIndustry，HenanKeyLaboratoryof 450002，Henan，China) SurfaceInterfaceScience，Zhengzhou Abstract：Thenon-isothermal behaviorof crystallizationpurelow-density and flame was differential LDPE／n-Si02compositecoatingpreparedby sprayinginvestigatedby scanning Avrami modified andMomodels various rates．The calorimetry(DSC)atcooling analysis byJeziorny coulddescribethe ofLDPEand non-isothermal LDPE／Si02compositecoating crystallizationprocess valuesof and，zincreasedwith rate．ThevaluesofZ。and咒of successfully．TheZo cooling