NiFeP粉煤灰漂珠磁性复合材料的制备与表征.pdfVIP

14 N-i Fe-P/ N-i Fe-P/ 1, 2 1 1 , , ( 1. , , 210046; 2. , 223001) [ ] 采用化学镀法在粉煤灰漂珠表面镀覆了N-i Fe-P 合金层, 制备了N-i Fe-P/ 漂珠磁性复合材料, 并 对其合成机 进行了分析利用SEM, EDX, XRD 及VSM 对化学镀前后漂珠的表面形貌成分结构及磁性能 进行了表征结果表明: 化学镀后漂珠表面包覆了均匀致密的N-i Fe-P 镀层; 经不同温度热处 后,镀态镀层的 非晶相结构转变为晶相结构; N-i Fe-P/ 漂珠复合粉体具备软磁材料的特性, 且随着镀层中铁含量的增加和热处 温度的升高, 复合粉体的磁性能得到明显改善 [] 化学镀; N-i Fe-P 合金; 粉煤灰漂珠; 磁性能 [ ]TQ153.2;T 332 [ ] A [] 1001-3660(2011) 04-0014-05 Preparation and Characterization of Magnetic Composites of N-i Fe-P/ Fly Ash Cenospheres 1, 2 1 1 PANG J ia n-f eng , LI Qin , ZHAI J ian-p ing ( 1. State Key Laboratory of Pollution Control and Resource Reuse, School of Environment, Nanjing University, Nanjing, 210046, China; 2. H uaiyin Institute of T echnology, Huai. an 223001, China) [Abstract] The magnetic composites of N-i Fe-P/ fly ash cenospheres ( FACs) were preparedby coating FACs with N-i Fe-P alloy films through an electroless plating w ay. And the formation mechanism of the N-i Fe-P alloy deposits was analyzed. The morphology, composition, crystal structure andmagnetic properties of composite pow ders were character- ized by SEM, EDX, XRD and VSM techniques. The results show that the continuous and uniform coatings are obtained on the surfaces of the FACs. In addition, it is found that the as-plated deposits are N-i Fe-P alloy microparticles, which transformed from amorphous state to crystal phases with the increase of calcining temperature. Furthermore, the elec- troless N-i Fe-P deposits exhibite soft magnetic properties. The magnetic performances of the deposits will be ameliorated with the increase of the iron content of the coati