大尺寸煤基炭泡沫制备工艺初步的研究(终极打印版)6.14.doc

大尺寸煤基炭泡沫制备工艺的初步研究 摘要本文以焦煤、肥煤和气煤分离富集的镜质组富集物为原料，采用高压发泡法制备泡沫炭。实验主要研究了不同前驱体和压力对泡沫炭气孔率和抗压强度的影响。气孔参数通过真密度和体密度计算，利用SEM观察气孔的形貌，PLM进行孔径分布表征，利用CTM8020型微机控制电子万能材料试验机检测材料的抗压强度。实验结果表明：分别用焦煤镜质组、气煤镜质组和肥煤镜质组富集物为原料制备泡沫炭时：肥煤镜质组制备的泡沫炭气孔率最大（64.19%）、气煤镜质组次之（61.64%）、焦煤镜质组最小（56.30%）。焦煤镜质组富集物制备的炭泡沫孔径分布相对较窄，其次为气煤镜质组富集物制备的炭泡沫。而肥煤镜质组制备的炭泡沫孔径分布很宽，并且存在很多大孔。焦煤镜质组制备的泡沫炭抗压强度最大、气煤镜质组次之、肥煤镜质组最小，抗压强度分别为：26.348MPa、24.963MPa、9.947MPa。而且随着气孔率的升高，抗压强度降低。在相同前驱体和相同工艺条件的前提下，炭泡沫的气孔率随着压力的增加呈现下降的趋势。而且随着压力的增加，孔径分布越来越窄，试样的上中下的孔径均匀。泡沫炭炭化后气孔率均减小，但是变化不太明显，真密度、体密度均增大。 A Preliminary Study on Carbon Foam with Large Size and Cylinder ABSTRACT Carbon foams were prepared using vitrinite-rich concentrates of three bituminous coals. The porosity, pore diameter distribution, morphology and compressive strength were studied. The bulk density was tested by volume. The true density is measured using a pycnometer based on GB / T217 -1996. The open porosity is calculated by the bulk density and the true density. The morphology of the carbon foams obtained in this study is characterized by scanning electron microscopy (SEM), and the pore diameter distribution was tested by PLM. The results show that the open porosities of carbon foam from vitrinite-rich concentrates of gas coal, fat coal and coking coal are 64.19%, 61.64% and 56.30%. The pore diameter distribution of carbon foam from vitrinite-rich concentrates of coking coal is maximum and it from vitrinite-rich concentrates of fat coal. With the initial pressure and final pressure increasing the porosity of carbon foam is reduced and the pore diameter distribution gets narrow gradually. The compressive strength of all sample are all more than 9MPa and the fracture behavior of carbon foam exhibits pseudo-plastic. Key words:?carbon foam;?vitrinite; porosity; coal 目 录 摘要 I 1 文献综述 1 1.1 泡沫炭 1 1.1.1 泡沫炭的发展史 1 1.1.2 泡沫炭的结构 2 1.1.3 泡沫炭的性能 3 1.1.4 泡沫炭的应用与发展前景 5 1.1.5 泡沫炭的制备原料与方法 8 1.2 本文的研究内容及意义 13 2 实验 14 2.1 主要实验设备 14 2.2 实验原理 15 2.3 实验原料 15 2.3.1 原料的制备 15 2.3.2 原料分析 15 2.4 实验方案 1