LiFePO_4正极材料制备过程研究进展.pdfVIP

化 工 进 展 ·1508 · CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2010 年第29 卷第8 期 进展与述评 LiFePO4 正极材料制备过程研究进展 李景坤，廖小珍，马紫峰 （上海交通大学化学工程系，电化学与能源技术研究所，上海 200240 ） 摘 要：基于磷酸铁锂正极材料的动力锂离子电池是近年来最受关注的电动汽车动力电源之一。由于原料路线 差异，磷酸铁锂正极材料制备工艺有多种。本文回顾了上海交通大学在磷酸铁锂正极材料制备过程设计与研究 中所取得的进展。在国家重点基础研究发展计划（国家 973 计划）支持下，重点研究了磷酸铁锂正极材料制备 过程及其充放电倍率特性，还提出了如何改善磷酸铁锂正极材料在不同环境温度下性能的解决途径。最后，介 绍了LiFePO4/C 正极材料制备过程中涉及的还原过程、碳源选择和制备过程装备等过程工程特性问题。 关键词：磷酸铁锂（LiFePO4 ）；正极材料；制备过程；电化学性能 中图分类号：TM 912.9 文献标识码：A 文章编号：1000 –6613 （2010 ）08 –1508 –05 Research progress in preparation process of LiFePO cathode materials 4 for lithium ion battery LI Jingkun ，LIAO Xiaozhen ，MA Zifeng （Institute of Electrochemical and Energy Technology ，Department of Chemical Engineering ， Shanghai Jiao Tong University，Shanghai 200240，China ） Abstract：Lithium iron phosphate （LiFePO4 ）has received particular interest as cathode materials for large-size lithium-ion batteries in electric vehicles application. The preparation process of LiFePO4 varies with starting materials. This paper reviews the research progress in various synthetic routes for LiFePO4 developed by Shanghai Jiao Tong University with focus on the preparation process of LiFePO4/C and its charge-discharge performance. Approaches to improve the performance of LiFePO4/C cathode in different working temperature range are also presented. Finally ，the process engineering problems of LiFePO4/C cathode material preparation are discussed ，including the effects of reductant ，carbon source and pro