Highly selective detection of Hg2+ ion by push–pull-type purine nucleoside-based fluorescent sensor》.pdfVIP

Tetrahedron 70 (2014) 4929e4933 Contents lists available at ScienceDirect Tetrahedron journal homepage: www.el /locate/tet Highly selective detection of Hg2þ ion by pushepull-type purine nucleoside-based fluorescent sensor Shao-Hua Gao a, Ming-Sheng Xie a, Hai-Xia Wang a, Hong-Ying Niu b, Gui-Rong Qu a, *, Hai-Ming Guo a, * a Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, School of Chemistry and Chemical Engineering, Henan Normal University, Xinxiang, Henan 453007, PR China b School of Chemistry and Chemical Engineering, Henan Institute of Science and Technology, Xinxiang 453003, China a r t i c l e i n f o a b s t r a c t Article history: Highly selective detection of Hg2þ ion has been achieved using the pushepull-type purine nucleoside- Received 18 January 2014 based fluorescent sensor L1. The sensor L1 incorporating aza-18-crown-6 at C6 position of purine Received in revised form 7 May 2014 nucleoside, is highly sensitive and selective toward Hg2þ ion in CH CNeH O mixture (92/8, v/v). The 3 2 Accepted 15 May 2014 2þ 8 detection limit for the fluorescent sensor L1 toward Hg ion is 7.8 10 . Available online 20 May