《块体超细晶FeNiCr合金的腐蚀行为（英文版）》.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 1989−1994 Electrochemical corrosion behavior of bulk ultra-fine grained Fe−Ni−Cr alloy Zhan-wen WU1,2 1 1 3 1 3 1 , Ji CHEN , Nan PIAO , Cheng SUN , W. HASSAN , Xin-hang ZHANG , Yu-jun XIE 1. Department of Mechanical Engineering, Liaoning Shihua University, Fushun 113001, China; 2. CNOOC Energy Technology and Services–Pipe Engineering Co., Tianjin 300452, China; 3. Department of Mechanical Engineering, Materials Science and Engineering Program, Texas AM University, College Station, Texas 77843-3123, USA Received 20 May 2013; accepted 13 March 2014 Abstract: The corrosion behavior of bulk ultra-fine grained (UFG) Fe−Ni−Cr alloy prepared by equal-channel angular pressing technique was investigated in 0.25 mol/L Na SO +0.05 mol/L H SO solution by electrochemical measurements. As compared to the 2 4 2 4 coarse grained (CG) counterpart, the UFG alloy exhibits an acceleration of the active dissolution and a shrunk passive region with a higher passive current. The Mott−Schottky analysis in conjunction with the point defect model indicates that the donor diffusion coefficient in the passive films of the UFG sample increases greatly to one magnitude order higher and the donor density is slightly lower than that of the CG sample. Key words: stainless steel; Fe−Ni−Cr; polarization; acid corrosion; passivation nanocrystallization by magnetron sputtering accelerated