la改性znf2o4应用于乙二醇、尿素催化合成碳酸乙烯酯毕业论文.docVIP

La改性ZnFe2O4应用于乙二醇、尿素催化合成碳酸乙烯酯 Catalytic ynthesis Ethylene Carbonate Ester by Urea and Ethylene Glycol over La Modified ZnFe2O4 目 录 摘要 I Abstract II 引言 1 第１章 文献综述 3 1.1 概述 3 1.1.1 绿色化学技术 3 1.1.2 环状碳酸亚烃酯下游产品开发与应用研究进展 4 1.2 碳酸乙烯酯合成的研究 4 1.2.1 碳酸乙烯酯的性质和用途 4 1.2.2 碳酸乙烯酯合成研究的进展 8 1.3 尿素的性质和生产现状 11 1.3.1 尿素的性质 11 1.3.2 尿素的合成和应用 11 1.3.3 尿素生产现状 12 1.4 研究思路 13 第2章 合成催化剂 14 2.1 溶胶凝胶法 14 2.2 基本原理 14 2.3 实验装置 14 2.4 实验试剂 15 2.5 实验步骤 16 2.6 催化剂的表征 16 2.6.1 热重分析 16 2.6.2 X射线粉末衍射仪(XRD)分析 19 第3章 碳酸乙烯酯的合成 22 3.1 实验原理 22 3.2 碳酸乙烯酯合成反应方程式 22 3.3 实验试剂 22 3.4 碳酸乙烯酯合成条件的初定 23 3.5 实验步骤 23 3.6 碳酸乙烯酯的精制 24 3.6.1 重结晶原理 24 3.6.2 精制过程 24 3.7 产品热重表征 24 结论 26 致谢 28 参考文献 29La改性ZnFe2O4应用于乙二醇、尿素催化合成碳酸乙烯酯 摘要：碳酸乙烯酯作为电池的电解质，对光，热和化学变化等不利因素有较高的承受能力。近年来国家一直倡导低碳经济，绿色出行，电动汽车增长势头强劲，毫无疑问，电动汽车对电池的依赖性巨大，碳酸乙烯酯具有巨大的潜在应用市场。 调整锌、铁的配比用溶胶凝胶法制备经过热重检测挑选出相对好的两组催化剂La对其进行改性，并制成催化剂。改性后的催化剂用热重分析仪和X射线粉末衍射仪(XRD)检测，对比改性前后催化剂热和，催化剂 实验结果表明，加入La对铁酸锌系列催化剂改性，增加催化剂的比表面积，提高催化剂的。乙二醇合成碳酸乙烯。 关键词尿素 乙二醇 镧 铁酸锌 碳酸乙烯  Catalytic Synthesis Ethylene Carbonate Ester by Urea and Ethylene Glycol over La Modified ZnFe2O4 Abstract: Ethylene carbonate(EC) and propylene carbonate(PC) have the capacity of bearing light, heat and chemical changes of negative factors as the battery electrolyte. In recent years, low carbon economy, green travel have been advocating in many countries. Growth momentum of electric cars keep high speed dependency on battery without doubt. There is no doubt that electric cars mainly rely on battery. Therefore EC market has huge potential applications. The ratio of zinc and iron was changed for the requirements to prepare ZnFe2O4 catalysts by sol-gel method. Then ZnFe2O4 catalysts were detected by TGA to find out two catalyst with high activity. The catalysts was modified by La. The modified catalysts was detected by thermo-gravimetric Analysis (TGA) and X-ray powder diffractometer (XRD). The thermal effect curves and XRD spectra of modified and not modified catalysts were compared to seek the best metal atom ratio