新型硫掺杂聚苯乙烯的制备和表征.pdfVIP

447 V o l. 44, N o. 7 20 107 A t omic Ener gy Science and T echno logy J uly 2010 杨军校, 隋海波, 杨海君, 刘才林 ( , 62 10 10 : , ( A IBN , , , , , , , : ; ; ; ; : O 634 : A : 2010 Preparation and Characterization of New Type Sulfur Doped Polystyrene Y A N G Junxiao, SU I H aibo, Y A N G H aijun, L IU Cailin (S chool of M ater ials S cience and E ng ineer ing , Southw est Univ er sity of Sc ience and T ech nology , M iany ang 621010, Ch ina) Abstract: T he pr eparation m et hod of a new t y pe sulf ur doped polyst yrene w as st udied . Under t he init iato r o f A IBN , ho mopolym er and copolym er w it h st y rene w ere synthe sized f rom p chlo romet hyl st yrene. T he chlorom et hyl po lyst y rene can react w it h po tas sium ethy l xant hat e t o pr oduce sulf ur doped poly st yr ene. T his method is simple and the condit ion o f react ion is mild . T he st ruct ures of t he polym er w ere charact erized by means 1 of IR and H N M R. T he r elat ive molecular m ass o f poly mer w as det ect ed by g el perme at ion chr omat ogr am ( GPC and t he doped am ount of sulfur at om w as analyzed by ele m ent analysis. A t t he sam e t ime, t he per for mance o f f ilm f ormat ion was also st udied . T he init ial result s show t hat t he polym ers have a good f ilm charact er ist ic. Key words: inert ial conf inement f usio n; t arget m at erials; doping ; pot assium et hyl xan t hog enate; sulf ur ato m ( ICF , CH ON Z , , : : : : ( 197 1 , , , , , 7 :