生物质混煤燃烧过程中受热面金属氯腐蚀特性试验的研究.pdfVIP

第 33 卷 第 20 期 中 国 电 机 工 程 学 报 Vol.33 No.20 Jul. 15, 2013 88 2013 年 7 月 15 日 Proceedings of the CSEE ©2013 Chin.Soc.for Elec.Eng. 0258-8013 (2013) 20-0088-08 TK 6 A 470 20 文章编号： 中图分类号： 文献标志码： 学科分类号： ⋅ 生物质混煤燃烧过程中受热面金属 氯腐蚀特性试验研究 王永征，姜磊，岳茂振，栗秀娟，余滔 ( 山东大学能源与动力工程学院，山东省 济南市 250061) Experimental Study on Characteristics of Chlorine Corrosion to Heating Surface Metal During Co-firing of Coal and Biomass WANG Yongzheng, JIANG Lei, YUE Maozhen, LI Xiujuan, YU Tao (School of Energy and Power Engineering, Shandong University, Jinan 250061, Shandong Province, China) ABSTRACT: Characteristics of chlorine corrosion to metal 情况，采用腐蚀增重方法，对生物质混煤燃烧过程中受热面 pipe material of heating surface during co-firing of coal and 金属管材的氯腐蚀特性进行了试验研究。结果表明，金属试 biomass were investigated using a self-designed horizontal tube 样的腐蚀增重量随时间增加而增大，符合抛物线规律。在初 furnace. Corrosion mass gain method was taken to accomplish 期存在快速腐蚀阶段，生成保护薄层，随后腐蚀逐渐变缓。 the analyses. The results show that the corrosion mass gain of 随着生物质掺混比例的提高，反应速率在快速腐蚀阶段成比 metal samples increases with time, and the curves conform to 例增加，而后期变化不大。涂灰在初期显著降低试样腐蚀速 parabola. The chlorine corrosion rate of metal samples is high 率，随后受到灰中 Cl、S 等成分作用，涂灰金属试样一直保 at the initial stage, and then gradually decreases due to the 持较高的腐蚀速率，最终比未涂灰的试样腐蚀严重，且受涂 protective effect of thin film formed in corrosion reaction. With 灰量和成灰温度影响较大。温度对腐蚀速率的影响符合 the increase of the proportion of biomass blended to coal, the Arrhenius 定律。随着气相中 HCl 浓度升高，金属试样的腐 corrosion rate of metal samples increases i