BDADEEA两相吸收剂吸收CO2的研究.pdfVIP

34 5 Vol.34, No.5 2013 5 JOURNAL OF ENGINEERING THERMOPHYSICS May, 2013 BDA/DEEA CO2 ( 100084) BDA(1, 4- Æ) DEEA(N, N- Æ) Æ ÆCO2 CO2 Æ 2 mol/L BDA+4 mol/L DEEA (2B4D) CO2 97.4%91% CO2 Æ CO2 CO2−/HCO− 3 3 CO2 BDA DEEA : TQ028 : A : 0253–231X(2013)05–0993–05 CO2 Absorption by BDA/DEEA Biphasic Solvents XU Zhi-Cheng WANG Shu-Juan CHEN Chang-He (Key Laboratory of Thermal Scicence and Power Engineering of the Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China) Abstract The mixtures of 1,4-Butanediamine (BDA) and 2-(Diethylamino)-ethanol (DEEA) were N found to be efficient biphasic solvents. The best concentration was identified and compared using C a fast screening facility. The individual amine distributions in the upper and lower phases were T. measured by DX-120 ion chromatography (IC), with the reaction products of amine and CO2 studied E by a JNM ECA-600 nuclear magnetic resonance spectrometer (NMR). The results show that the best I solution was the blend of 2 mol/L BDA and 4 mol/L DEEA (2B4D). The CO2 in the lower phase was . 97.4% of the total absorbed CO2 . And 91% of absorbed CO2 was converted into carbamate, while P th