疏水缔合水溶性聚丙烯酰胺类化合物的合成、性能及界面行为研究.pdf

疏水缔合水溶性聚丙烯酞胺类化合物的合成、性能及界面行为研究 在快速的交换过程，而这种交换过程不可避免地导致聚合物链发生构象的变化; 当聚合物体相浓度足够大时 (接近其临界缔合浓度)，界面上的疏水嵌段也会形 成类似体相中的聚集体，此时聚合物界面吸附膜的性质主要由疏水嵌段与界面聚 集体之间的快速交换过程控制;表面活性剂对疏水缔合聚合物的界面膜性质有较 大影响，它与聚合物的疏水嵌段在界面上可能形成类似于混合胶束的聚集体，表 面活性剂分子与界面聚集体间的交换比疏水嵌段与聚集体间的交换更快，能强烈 改变界面膜的性质。 关键词:疏水缔合聚合物;溶液性能;界面扩张粘弹性;弛豫过程;扩张模量; 相角 摘 要 ABSTRACT Inthispaper,fourkindsofwater-solublehydrophobicassociating P(AM/OA),P(AM/2-ERA)、P(AM/CHEA)和 P仍M/PEA),composedofacryl amide(AM)and a smallamountofn-octalAcrylate(OA),2-EthylhxylAcryl ate(2-EHA),CyclohexylethylAcsylate(CHEA)andphenethylAcrylate(PEA) (=1.Omol%)weresynthesizedbyamicellarcopolymerization techniqueand characterizedbyHNMR,TG,DSC. Thesolutionpropertywasinvestigated.Itwasfoundthattheyexhibitanability ofhydrophobicallyassociatingandeasylyundergointer-molecularinteractionwhich resultinginadramaticallyincrease ofsolutionviscosity.Thenfactorsinfluencing theologyproperty,suchaspolymerconcentration,temperatureandsalinity,werealso studied.Theresultsobtainedindicatedthatthecopolymersexhibitahighassociation propertyandahighsalttolerance. Theaggregationbehaviorofcopolymerswasfurtherinvestigatedinaqueous solutionsbysteady-statefluorescencespectroscopy,HNMR,twodimensional NOESY,transmissionelectronmicroscopyandscanningelectronmicroscopy.Itwas foundthatthecopolymersformamulti-polymermicelle-likeaggregate.Asthe concentrationincreasing,theaggregateswere furthermoretoform a networkstructure,whichcanwellexplainthebehaviorofviscosityincreasing. Theinterfacialdilationalviscoelasticpropertiesofhydrophobicallyassociating blockcopolymerP(AM/2-EHA)withahydrolyzeddegreeofabout1.5-2.0%atthe octane-waterinterfaceswereinvestigatedbymeansoftwomethods:theinterfacial tensionresponsetosinusoidalareavariations(oscillatingbarriersmethod)andthe relaxationofanappliedstress(interfacialtensionrelaxationmethod)respectively Thedependenciesofinter