热处理温度对TiSnO2-Sb2O5电极的电催化性能的影响 毕业论文.doc

毕业设计（论文） Ti/SnO2-Sb2O5电极的电催化性能的影响 摘 要 钛基Sn02掺杂DSA电极是文献报道中的电催化性能最为优越的电极材料之一本文综述了掺Ti/SnO2-Sb2O5电极的制备方法及其特点（主要有喷雾热解法化学气相沉积法、氧化浸透涂层法、涂层热解法、溶胶-凝胶法），介绍了掺Ti/SnO2-Sb2O5电极的应用现状。以SnCl4·5H2O、SbCl3和2O3为原料，采用涂层热解法制得了Ti/SnO2-Sb2O5电极。采用X-射线衍射（XRD）、扫描电镜观察（SEM）等检测方法对电极的锡锑氧化物涂层的晶体结构、粒径和形貌进行了研究。采用电化学分析仪和可见分光光度计共同检测掺Ti/SnO2-Sb2O5电极的电催化性能。结果表明 关键词 Sn/Sb电极，涂层热解法，电化学性能 ABSTRACT 。This paper reviews the preparation of Sm-doped Ti/SnO2-Sb2O5 electrode methods and characteristics (mainly spray pyrolysis，chemical vapor deposition，oxidation of saturated coating method, coating pyrolysis, sol-gel method), . To SnCl4 ? 5H2O, SbCl3 and Sm2O3 as raw materials，coating pyrolysis method got different amount of doped europium Ti/SnO2-Sb2O5 europium-doped electrodes. By X-ray diffraction (XRD), scanning electron microscopy (SEM) testing methods such as antimony tin oxide electrode coated crystal structure, particle size and morphology were studied. Electrochemical analyzer and a common test Spectrophoto meter Ti/SnO2-Sb2O5 Sm-doped catalytic electrodes. Results show that the heat treatment temperature on the T I/SnO2 - Sb2O5 electrode influenced the electrode life, heat treatment temperature for 450 ℃ electrode electrode life than other heat treatment temperature of electrode electrode life gets smaller. 450 ℃ electrode surface coating have big pore, coating and matrix adhesion of relatively weak, coating, and fall in electricity to degradation process solution can easily penetrate to the electrode, TiO2 matrix formed the conductivity of insulating layer, reducing electrode, accelerate the electrode coating, so the dissolution of 4.5 ℃ electrode electrode life obviously lower than other three electrodes. Heat treatment temperature for 550, 650 ℃ electrode surface, 750 even coating, density, crack small, electrode life are 450 ℃ electrode electrode life more than twice as much. But 750 ℃ electrode because of higher temperature, heat treatment and coating on the electrode matrix formed between TiO2 passi