我的毕设电沉积Ni-W-P合金镀层要点解读.docx

兰州理工大学毕业论文  PAGE \* MERGEFORMAT IV 摘 要 电沉积非晶Ni-W-P合金镀层硬度高，耐蚀耐磨性好，热稳定性高，并具有良好的物理化学性能和一些特殊功能，如磁性能、催化性能等，因此科学界对发展Ni-W-P合金非常感兴趣。但电沉积Ni-W-P合金同时也存在镀液成本高、稳定性较差以及镀层质量达不到要求等不足。针对这些不足，在前人研究基础上，优化电沉积Ni-W-P合金工艺，成功配制出稳定性高、寿命较长的镀液，并获得质量较高、性能优异的镀层。 选取硫酸镍、次亚磷酸钠、钨酸钠作为镀液主盐，硼酸作为缓冲剂，柠檬酸钠作为络合剂，糖精为去应力剂，十二烷基硫酸钠为表面活性剂。通过实验研究取得以下结果： (1)当电镀液中亚磷酸的含量为20g/L时，获得的合金镀层性能最优良，具有很高的抗氧化性； （2）在进行高温氧化处理过程中，当温度超过300℃时，非晶态镀层就会向晶态转化，当温度超过500℃时完全晶化.继续加热，晶粒变粗，抗氧化性会降低。 关键词:电沉积；Ni-W-P合金；镀层；高温氧化 Abstract An interest has been taken in developing electroplating ternary Ni-W-P alloy for its excellent properties in the scientific community, such as high hardness, wear and corrosion resistance and thermal stability, good physical and chemical properties and some special functions, such as magnetism, catalysis, etc. But there are some problems and deficiencies, for example, the high cost and the poor stability of plating solution, and the poor quality of the deposit, etc. In view of these weaknesses, the paper aims to optimize the process of electroplating Ni-W-P alloy on the basis of predecessors. Finally, the coating with superior quality and performance is prepared successfully, and at the same time the solution has longer service cycle and higher stability. Selection of nickel sulfate, sodium phosphate, sodium tungstate as main salt solution, boric acid as buffering agent, sodium citrate as complexing agent, saccharin as to stress agent, sodium dodecyl sulfate as surfactant. The results of the experiment are as follows: (1) when the content of the acid in the middle of the plating bath is 20g/L, the alloy coating has the best performance and has the high oxidation resistance. (2) in the high temperature oxidation process, when the temperature higher than 300 ℃, amorphous coating will to crystalline transformation, when the temperature of more than 500 ℃ complete crystallization. Continue to heat, grain coarsening, oxidation resistance will be reduced. Keywords: electro-deposition; Ni-W-P alloy; platin