光致界面电荷转移教程方案.pptxVIP

工作汇报;金属功函数Wm：把金属中电子从费米能级EFm逸出到真空E0中所需的最小能量称为金属的功函数; 本征激发：当半导体从外界获得一定的能量，受到激发，电子从价带顶端跃迁到导带底端，而产生出自由电子和自由空穴的现象。 本征激发的容易程度受到禁带宽度的影响。 ;透明导电玻璃;透明导电玻璃;光致界面电荷转移的机理;文献;CuTsPc supramolecular films and CuTsPc LB films with space in the lipid chain were prepared on p-Si(III) using the LB technique. The surface photovoltage spectra of both film systems were measured for the first time. It was found that the surface photovoltaic effect of the film systems was at a maximum when only one monolayer of CuTsPc molecules was modified on p-Si(III). Our experiments indicated that only the first CuTsPc monolayer adjacent to the semiconductor plays a key role in the light-induced interfacial charge transfer.;1. Introduction;Recently, our group successfully prepared a new kind of ultrathin CuTsPc molecular film which has some characteristics of a one-dimensional conductor . the supramolecular films and CuTsPc LB films with space in the lipid chain were prepared on p-Si(III), and the dependence of their photovoltaic response on the film thickness was studied by surface photovoltage spectroscopy. ;2. Experimental;The wafer was then washed with pure water and dried. ;In order to protect the molecular films, a contactless measurement method was used: a thin sheet of mica with a circular hole 7 mm in diameter was placed between the electrodes and the measured sample.;3. Results and discussion;表面光电压是固体表面的光生伏特效应?,是光致电子跃迁的结果。 “光生伏特效应”（ Photovoltaic effect），简称“光伏效应”。 光伏效应指光照使不均匀半导体或半导体与金属结合的不同部位之间产生电位差的现象。;As a comparison, we prepared CuTsPc LB multilayers with space in the lipid chain on p-Si(III), and measured their surface photovoltage spectra (Fig. 4). ;The results support the aforementioned conclusions. Furthermore, the surface photovoltaic signal decreases more rapidly than in the free-lipid CuTsPc supramolecular film with increasing number of layers. It is obvious that the CuTsPc monolayers are separated from each other by the lipid chain, which inhibits the carrier trans