精馏法处理钼酸铵生产中的高浓度氨氮废水.docVIP

PAGE  doi：10.3969/j.issn.1007-7545.2015.11.018 精馏法处理钼酸铵生产中的高浓度氨氮废水 刘晨明，林晓，陶莉，田萍，李金涛，曹宏斌 （中国科学院 过程工程研究所，湿法冶金清洁生产技术国家工程实验室，北京市过程污染控制环境工程研究中心，北京 100190） 摘要：采用中和—过滤—换热—精馏—氨水回收的工艺处理钼酸铵生产废水，研究了各工艺参数对脱氨效果的影响、硫酸钙结垢机理和阻垢剂的阻垢性能与原理。结果表明，将pH调节至12.5以上能有效去除铜氨络离子，进而较彻底地去除氨氮；精馏塔的关键操作参数优化值为：塔釜温度105 ℃，蒸汽压力不低于0.3M Pa，优化后的精馏工艺，能够实现精馏设备的稳定运行和排水达标。阻垢剂在硫酸钙结垢形成之前添加效果最佳，阻垢原理为阻止溶解度较高的α-硫酸钙转化为溶解度较低的二水硫酸钙，从而提高结垢的浓度阈值。 关键词：钼酸铵；氨氮；精馏；阻垢；废水处理 中图分类号：X703 文献标志码：A 文章编号：1007-7545（2015）11-0000-00 Distillation Treatment on High-concentration Ammonia Nitrogen Wastewater from Ammonium Molybdate Production LIU Chen-ming, LIN Xiao, TAO Li, TIAN Ping, LI Jin-tao, CAO Hong-bin （Institute of Process Engineering, Chinese Academy of Science, National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology, Beijing Research Centre for Process Pollution Control, Beijing 100190, China） Abstract：Wastewater from ammonium molybdate production was treated by neutralization, filtration, heat exchange, distillation, and ammonia solution recovery. The effect of process parameters on ammonia removal efficiency, mechanism of calcium sulfate scaling, mechanism of scale inhibition and performance of scale inhibitor was investigated. The results show that copper ammonia complex is broken and ammonia is relatively thoroughly removed by adjusting pH value to 12 above. The distillation column operates steadily and water draining meets the standard with ammonia efficiently recovered under the optimum operation parameters of distillation column including temperature of 105 ℃ and steam pressure of 0.3 MPa below. Scale inhibitor is to be added before formation of calcium sulfate scaling for the best. The mechanism of scale inhibition is to prevent high solubility of α-calcium sulfate from transforming into low solubility of dehydrate calcium sulphate, so as to increase concentration threshold of scaling. Key words：ammonium molybdate; ammonia nitrogen; distillation; scale inhibition; wastewater treatment 2