参考资料--液相法制备纳米结构及特性研究.docVIP

液相法制备纳米结构及特性研究 摘 要 三氧化钼因其具有的特殊结构，非常适合其它小分子或离子的嵌入而受到越来越多的关注，这种特殊的层状结构使得三氧化钼具有良好的电致变色、光致变色、催化和气敏等性能。在合成敏感元件、显示设备、智能窗、润滑油、催化剂、快离子导体以及潜在的电池电极等许多功能材料方面具有特殊的用途。与块状或几微米级三氧化钼比较，纳米三氧化钼的催化活性明显提高。对某些化学反应而言其催化作用要高出几倍甚至十几倍。纳米三氧化钼的耐蚀性和耐氧化性也高于传统三氧化钼。其他特性如光学电学性能等尚在研究中。此外纳米三氧化钼是某些材料生产的前体，如钼粉、钼铝复合材料、碳化钼、氮化钼和钼钨复合材料等 制备纳米的各种流程：其中包括沉淀法、水热法、CVD法、溶胶一凝胶法、共胶凝法、微波水热法等。本文简要介绍了其中的水热法、沉淀法、溶胶凝胶法、微波水热法制备的制备流程与表征，并总结了这几种方法的优点和缺点。 三氧化钼，制备，性质，反应时间，反应流程 ABSTRACT Molybdenum trioxide is geting more and more attention because of its special structure, being very suitable for other small molecules or ions embedded, this special layer structure makes the electrically induced discoloration of molybdenum trioxide has good, photochromic and catalytic gas sensitive performance.In the synthesis of sensitive element, display devices, smart Windows, lubricants, catalysts, fast ion conductors as well as potential battery electrodes in many functional materials with special purposes. And block or several micron grade molybdenum oxide, nano molybdenum oxide catalytic activity increased significantly. For some chemical reaction the catalyst to several times or even dozens of times higher. Nano molybdenum oxide corrosion resistance and oxidation resistance is higher than the traditional molybdenum trioxide. Other features such as optical electrical performance is still in the study. Moreover nano molybdenum trioxide is a precursor of certain materials, such as molybdenum powder, molybdenum, aluminum composite material, molybdenum tungsten and molybdenum carbide and molybdenum nitride composite materials, etc Preparation of nanometer process: including precipitation method, hydrothermal method, a CVD method, sol-gel method, total gelation method, microwave hydrothermal method, etc. This paper briefly introduces the hydrothermal method, precipitation method, sol-gel method, the preparation process and the characteristic of microwave hydrothermal method, and summarizes the advantages and disadv