溶胶凝胶制备TiO2.ppt

Sol-gel Method Sol-gel Method in Preparation of Titania Nano-powder Reporter：戴　雷 Smembers：杜　刚 S 厉艳君 S 邵 芳 S 陈 芳 S 2008年12月 Outline Introduction of TiO2 nano-powders General synthesis of TiO2 powders Preparation of TiO2 powders by sol-gel 1.Introduction photocatalytic electrochromic high-dielectric constant sensing properties photocatalytic capacitors smart window photovoltaic TiO2 applications gas sensor Applications smart window gas sensing devices air cleaner Photocatalytic Applications the most efficient and environmentally benign photocatalyst Applications TiO2 nanocrystalline electrodes Applications the dye-sensitized nanocrystalline solar cell Applications Photocatalytic Water Splitting the photocatalytic reaction cell for splitting water Lattice structure of TiO2 O2-ions are in CCP Crystal system: tetragonal Unit cell dimensions a = 3.7845 ? c = 9.5143 ? O2-ions are in HCP Crystal system: tetragonal Unit cell dimensions: a=4.5937 ?; c=2.9587 ? Lattice structure of TiO2 Anatase Rutile 2.General synthesis of TiO2 powders Hydrolysis Method Physical Vapor Deposition Chemical Vapor Deposition Precipitation hydrothermal method Sol-Gel …… Hydrolysis Method simple equipment low energy High purity high-cost Physical Vapor Deposition (PVD) high purity small size finely dispersed the technology and equipment finely dispersed on a large scale small size expensive hard to collect and store the powder Chemical Vapour Deposition (CVD) low-cost small size homogenous distribution impure precipitate is usually gel Precipitation Method Hydrothermal Method Certain concentration TiCl4 solution Putting into reactor precipitate Aging at 65-120℃ TiO2 powder centrifugation , washing, drying small size