原位红外技术.docxVIP

原位红外技术研究CuxO/TiO2有机污染物光降解的作用摘要：本工作采用改进的溶胶-凝胶法和浸渍法制备了TiO2 与另一半导体Cu2O组成的CuxO/TiO2光催化剂，运用XRD、N2 吸附脱附、紫外可见漫反射光谱(DRS)、表面光电压谱(SPS)等手段进行表征，同时利用原位红外技术考察了CuxO/TiO2 样品光催化降解乙烯、丙酮、苯的气-固相光催化氧化反应，对其光催化降解有机污染物的过程进行了研究。结果表明，TiO2 与另一半导体Cu2O复合后，锐钛矿晶型的含量增加，晶粒度减小，比表面积增大，禁带宽度增加，表面光电压信号增强，光生电子-空穴对有效分离；CuxO/TiO2 样品对乙烯、丙酮、苯的光催化性能与纯TiO2 相比均有不同程度的改善，乙烯可以被光催化氧化完全矿化生成CO2，而丙酮被光催化氧化可能生成中间产物丙酸，苯被光催化氧化可能生成中间产物苯酚和苯醌。关键词：TiO2；CuxO/TiO2；光催化氧化；原位红外光谱；有机污染物In Situ FTIR Study on Photocatalytic Degradation of Organic Contaminants over CuxO/TiO2Abstract : The CuxO doped TiO2 photocatalyst was prepared by the improved sol-gel and impregnation method.XRD, N2 adsorption, UV-Vis diffuse reflection spectroscopy and surface photovoltage spectroscopy (SPS) were ap-plied to study the effect of CuxO doping. At the same time, the photocatalytic process of TiO2 and CuxO doped TiO2 catalysts for degradation of ethylene, acetone, benzene were further studied by means of in situ FTIR. The result indicated that CuxO doping could enhance the photocatalytic activities of ethylene, acetone, benzene to some ex-tend as compared with pure TiO2. The increase in photoactivity is probably due to higher content of anatase,smaller particle size , higher specific surface area and lager band gap. In addition, the higher photocatalytic activity of CuxO doped TiO2 may be attributed to the stronger photovoltage signal and the effective separation ofphotogenerated electron-hole pairs. The result also showed that ethylene could be photocatalytically oxidized to CO2.The acetone and benzene may be photocatalytically oxidized to propionic acid and phenol, quinone, respectively.Keywords: TiO2; CuxO doping; photocatalytic oxidation; in situ FTIR; organic contaminants.近年来，随着建筑装饰材料、化学物质的大量使用，汽车、摩托车尾气及工业废气等直接向空气排放，空气污染越来越严重，已经引起人们的广泛重视。以TiO2 半导体为主的多相光催化氧化技术因与传统污染处理技术相比具有许多优点而倍受青睐，但是，由于光生载流子易于复合，因而无法从根本上解决量子效率较低的问题。金属离子掺杂是改善催化剂光催化性能的有效途径，在TiO2 中掺杂适量的其它金属离子，具有降低电子-空穴对的复合率、增加表面羟基位和改善光催化效率等作用[1~3]。稀土离子由于具有特殊的电子结构能有效地对TiO2 进行表面改性。目前，TiO2 掺杂稀土离子的光催化剂主