2012_No4_Chapters 6-8.pptVIP

Alternat 1 * Alternat 1 * Alternat 1 * Activity 0 1 2 3 4 A 0 0 1 1 2 ideal increasing non-ideality important effects of non-ideality Demixing (1) ‘i’ moves to regions with higher concentrations demixing spinodal points Demixing (2) 0 2 4 A, non-ideality critical point 0 1 one liquid two liquids spinodal curve binodal curve(phase boundary) unstable Supersaturation: metastable Maxwell Stefan: non-ideality in the driving force: example: Fick: non-ideality in the diffusivity: MS versus Fick thermodynamic correction factor ？ Fick and MS Diffusivities 1 0 -1 0 1 1 2 3 4 5 D’s positive, well behav