2010级炼铁-chIII-2.ppt

3. Physical chemistry of BF Processing Vaporization, decomposition and gasification Reduction process Slagging process Combustion reaction of carbon 3.4 Combustion reaction of carbon ? C + 1/2O2 = CO + 9791 kJ/kgC (2340 kcal/kgC) C + O2 = CO2 + 33388 kJ/kgC(7980kcal/kgC) 2CO + O2 = 2 CO2 C + CO2 = 2 CO ? C + H2O = H2 + CO ? 6911 kJ/kgH2O C + 2 H2O = 2 H2 + CO2 At combustion zone, high T and surplus carbon, so the main product is CO 3.4.1 The general rule of combustion reaction 3.4.2 The combustion in front of tuyere Combustion zone: the area before the tuyere where the carbon combusting to CO, also called the tuyere raceway or oxidization zone. It is the only oxidization area in BF. 3.4.2.1 Combustion zone The boundary of combustion zone is where the CO2 disappeared (or where the %CO21%). Its size is defined as the length of the raceway, generally 1000-1500mm Out of the raceway, the carbon oxide is only CO, and the main gas composition is CO + H2 + N2 The function of combustion zone Supply heat Supply CO Supply space for the burden material descending 3.4.2.2 The influencing factor of combustion zone size The raceway size are mainly lied on the penetration depth of oxidation gases (O2, CO2 and H2O). And this depth is decided by the blowing kinetic energy and combustion reaction rate (1) Blowing kinetic energy (E)——to describe the penetration ability of blast ↑ blast volume, blast Temp.,↓tuyere diameter,then E ↑↑, and the reaceway size ↑↑ (2) Combustion reaction rate v v ↑, combustion zone size ↓ T ↑ , v↑ O2 ↑ , v↑ 3.4.2.2 The influencing factor of combustion zone size Hot blast composition: O2 + N2 + H2O Combustion reaction: 2C + O2 = 2CO C + H2O = H2 + CO Hearth gas composition: CO + N2 + H2 3.4.2.3 The composition of BF hearth gas To calculate the composition of BF hearth gas, there are 3 methods (calculate unit): (1) 1Kg carbon; (2) 1m3 air; (3) 1t hot metal To begin the calculation, some definitions: ? : O2 content i