PhaseEquilibrium-UniversityofMinnesotaDuluth.ppt

* * * * * * * * * * * * * * * * * * * * * * Eutectoid: solid phase in equilibrium with two solid phases S2 S1+S3 ? ? + Fe3C (727oC) intermetallic compound - cementite cool heat Peritectic: liquid + solid 1 in equilibrium with a single solid 2 (Fig 9.21) S1 + L S2 ? + L ? (1493oC) cool heat Eutectic: a liquid in equilibrium with two solids L ? + ? Eutectoid Peritectic – some definitions cool heat Eutectoid Peritectic Cu-Zn Phase diagram Adapted from Fig. 9.21, Callister 7e. Eutectoid transition ? ? + ? Peritectic transition ? + L ? Iron-Carbon (Fe-C) Phase Diagram ? 2 important points -Eutectoid (B): g T a + Fe3C -Eutectic (A): L T g + Fe3C Fe3C (cementite) 1600 1400 1200 1000 800 600 400 0 1 2 3 4 5 6 6.7 L g (austenite) g +L g +Fe3C a +Fe3C a + g L+Fe3C d (Fe) Co, wt% C 1148°C T(°C) a 727°C = T eutectoid A S R 4.30 Result: Pearlite = alternating layers of a and Fe3C phases 120 mm (Adapted from Fig. 9.27, Callister 7e.) g g g g R S 0.76 C eutectoid B Fe3C (cementite-hard) a (ferrite-soft) Max. C solubility in ? iron = 2.11 wt% Hypoeutectoid Steel Adapted from Figs. 9.24 and 9.29,Callister 7e. (Fig. 9.24 adapted from Binary Alloy Phase Diagrams, 2nd ed., Vol. 1, T.B. Massalski (Ed.-in-Chief), ASM International, Materials Park, OH, 1990.) Fe3C (cementite) 1600 1400 1200 1000 800 600 400 0 1 2 3 4 5 6 6.7 L g (austenite) g +L g + Fe3C a + Fe3C L+Fe3C d (Fe) Co , wt% C 1148°C T(°C) a 727°C (Fe-C System) C0 0.76 proeutectoid ferrite pearlite 100 mm Hypoeutectoid steel R S a w a = S /( R + S ) w Fe3C = (1- w a ) w pearlite = w g pearlite r s w a = s /( r + s ) w g = (1- w a ) g g g g a a a g g g g g g g g Hypereutectoid Steel Fe3C (cementite) 1600 1400 1200 1000 800 600 400 0 1 2 3 4 5 6 6.7 L g (austenite) g +L g +Fe3C a +Fe3C L+Fe3C d (Fe) Co , wt%C 1148°C T(°C) a adapted from Binary Alloy Phase Diagrams, 2nd ed., V