实验六EDTA配制、标定、铅铋连续滴定讲解.docxVIP

PAGE \* MERGEFORMAT7 EDTA配制、标定、铅铋连续滴定 吴凡 四川农业大学 雅安 625014 摘要 在EDTA标准溶液的配制和标定实验中，学习EDTA标准溶液的配制和标定方法；掌握配位滴定的原理，了解配位的特点。称取一定质量的乙二胺四乙酸二钠固体（AR）配成溶液，用ZnO基准物标定，并用二甲酚橙作为指示剂来标定EDTA的浓度。平行进行5次滴定，测得 EDTA的浓度为0.02275mol/L。 接着再用标定的EDTA溶液测量铅、铋混合液中铅、铋的含量。平行进行5次滴定，测得铋的浓度为0.00913mol/L，铅的浓度为0.00911 mol/L。然后进行回收率的测定，用标定的EDTA溶液测量铅、铋混合液和铅标准溶液中铅、铋的含量。平行进行5次滴定，测得铋的浓度为0.005286mol/L，铅的浓度为0.009225mol/L。根据回收率=（x2-x1）/s得，可得回收率。 关键词 EDTA； 基准物； 连续测定； 二甲酚橙 EDTA preparation 、calibration、Lead bismuth continuous titration Wufan Sichuan Agricultural University yaan 625014 Abstract In the EDTA solution as the standard of sulfide and calibration experiments, learning EDTA solution as the standard of sulfide and calibration method; Master the principle of coordination titration, understand the characteristics of the coordination. Say take a certain quality of ethylenediamine tetraacetic acid disodium solid (AR) match into solution. With ZnO primary standard calibration.And xylenol orange as the indicator to calibrate the concentration of EDTA. Parallel to 5 times titration to measure the concentration of EDTA is 0.02275 mol/L. Then use the calibration of EDTA solution measuring lead, bismuth mixture of lead, bismuth content. Parallel to 5 times titration, bismuth concentration measured 0.00913 mol/L, lead concentration is 0.00911 mol/L. Then the determination of recovery, with the calibration of EDTA solution measuring lead, bismuth mixture and lead standard solution of lead, bismuth content. Parallel to 5 times titration, bismuth concentration measured 0.005286 mol/L, lead concentration is 0.009225 mol/L. According to the recovery = (x1 x2 -)/s, have to recovery. Key words EDTA; Primary standard; Continuous measurement; Xylenol orange 前言 EDTA配合物特点：广泛配位性：它几乎能与所有Mn+配位形成螯合物;稳定性：5个五元环螯合物→稳定、完全、迅速;具6个配位原子，与金属离子多形成1：1配合物,能溶于水;与无色离子形成无色配合物；与有色金属离子形成颜色更深的同色配合物。标定EDTA溶液常用的基准物有Zn、ZnO、CaCO3、Bi、Cu、MgSO4′7H2O、Hg、Ni、Pb等。本文采用ZnO为基准物，二甲酚橙作为指示剂来标定EDTA的浓度。测定 Pb2+和 Bi3+均以二甲酚橙为指示剂。二甲酚橙属于三类甲烷类指示剂，易溶于水，它有七级