物理化学练习题细答案.docVIP

11级物理化学练习题 一、计算题 2mol某双原子理想气体300 K下，体积m3增10m3 ，计算该过程的W，Q，(U，(H，(S(A及(G。S1＝100。 解：由及代入数据可解得：T2=600K = 12.47kJ， Qp = (H = 17.46kJ， W = (U(Qp = 12.47 ( 17.46= (4.99 kJ = 40.34 J.K-1 ΔA= (U (((TS)= (U ( (T2S2―T1S1) = (U ( (T2(S1+)―T1S1) = (41.73 kJ ΔG= (H (((TS)= (H ( (T2S2―T1S1) = (H ( (T2(S1+)―T1S1) = (36.74 kJ 二、计算题 2 mol某双原子理想气体kPa下，300 K升至400K ，计算该过程的W，Q，(U，(H，(S(A及(G。S1＝100。 解：恒容W = 0 kJ (U = Q =