金属有机化学第七章.pptVIP

* C-C bond formation by C-H activation of aromatic molecules There are a number of examples of C-C bond forming reactions involving C-H activation of aromatic ring C-H bonds. These reactions can even be found in classic organic reactions (Friedel-Crafts alkylation). For a review see: Chem. Rev. 2002, 102, 1731. The metal catalyzed versions of these reactions that couple arenes and alkenes are very attractive because they represent perfectly atom economical reactions (every atom in the starting materials is found in the product). Chapter 7 Hydrocarbon Functionalization by C-H Activation Exampl