第三章自由基共聚合李扬高化楼311Tel87952444.pptVIP

* Q-e scheme To simplify the process of determine reactivity ratios, a semiempirical relationship has been developed that expresses the ratios in terms of constants that are characteristic of each monomer but independent of comonomer. P1 and Q2 are measures of the reactivity of radical and monomer related to resonance stabilization, e1 and e2 are measures of the polarity of the radical and monomer * Styrene was chosen as the standard and assigned value of Q=1.00 and e= - 0.80. Value of Q increase with increasing resonance stabilization, while e value become less negative as groups attached