冯玉军-中低渗油藏化学驱用聚合物.ppt

Switchable viscosity exposure to air over time 0 h 5 h 24 h 48 h 72 h 96 h 120 h ACKNOWLEDGMENTS PhD Students GUO Zanru CHU Zonglin ZHANG Yongmin HAN Yixiu SUN Yuhai CHEN Zhi LU Hongsheng CHEN Quansheng SU Xin LI Xiaolan LU Yongli WANG Jiuxia WU Yufeng XIE Zahnfeng WANG Yu HE Shuai LIU Hanbin ZHU Dingwei YIN Hongyao MU Meng Master Students FENG Dan WANG Yuejiao FEI Chenhong SHUAI Ya DONG Hongwei XIE Chenxin Funding PetroChina ZHANG Yongmin CHU Zonglin GUO Zanru Thank you! Shengli, the second largest oilfield in China, initiated their polymer flooding in late 1960s, and went into field trials in 1995. Meanwhile, they started surfactant-polymer flooding projects late 1990s. Now, the total production from both polymer flooding and SP flooding exceed 1.7 million tone of oil per year, represents the largest SP projects worldwide. * temperature 40degree, salinity 6000 mg/L. The harsh reservoir conditions put forward more strict requirement of chemical EOR methods. * * * (G. Chauveteau) 中低渗油藏聚合物驱面临的挑战（2）：机械降解 ? Elongational (extensional) flow F—internal tensile force —velocity gradient Lc—countour length ? Shear flow The faster the flow rate, the higher the extension rate ? (Maeker, 1975; Seright, 1981, 1982; Martin, 1981, 1984) Long linear polyelectrolyte Flexible random coil Shear+elonggation HPAM M?, MWD?, ? ? The lower the K, the higher the The higher the MW, the easier the degration (Sorbie, 1991) (Hamielec, 1973) Example of mechanical degradation Low MW polymers are less sensitive to shearing Low stability for high MW The stability of high molecular weight molecules is very low Number of molecules 0 5 10 15 20 25 30 35 40 Molecular weight (10^6 Daltons) 15M 25M 20M Very high stability stability Poor stability Low stability Very low stability Final viscosity The mechanical degradation is generated directly at the injection point The chemical degradation happens a few hours after injection and polymer solution is then stable Viscosity cPs Time Factors Brine (T