材料科学与工程基础习题评讲1.ppt

习题讲解 第一次作业 2.7 Give the electron configurations for the following ions: Fe2+, Fe3+, Cu+, Ba2+, Br-, and S2-. SOLUTION Fe2+ : 1s22s22p63s23p63d6 Fe3+ : 1s22s22p63s23p63d5 Cu+ : 1s22s22p63s23p63d10 Ba2+ : 1s22s22p63s23p63d104s24p64d105s25p6 Br- : 1s22s22p63s23p63d104s24p6 S 2- : 1s22s22p63s23p6 第二次作业 2.18 Offer an explanation as to why covalently bonded materials are generally less dense than ionically or metallically bonded ones. 共价键需按键长、键角要求堆垛， 相对离子键和金属键较疏松 第三次作业 3.48 Draw an orthorhombic unit cell, and within that cell a [121] direction and a (210) plane. 3.50 Here are unit cells for two hypothetical metals: a. What are the indices for the directions indicated by the two vectors in sketch (a)?  b What are the indices for the two planes drawn in sketch (b)? （a）direction 1, x y z Projections 0a b/2 c Projections in terms of a, b, and c 0 1/2 1 Reduction to integers 0 1 2 Enclosure [012] direction 2, x y z Projections a/2 b/2 -c Projections in terms of a, b, and c 1/2 1/2 -1 Reduction to integers 1 1 -2 Enclosure [11 2] （b）Plane 1， ∞：1/2 ：∞ ； 0：2：0 ； (020) Plane 2， 1/2：-1/2 ： 1 ； 2：-2：1； (2 2 1) 3.51* Within a cubic unit cell, sketch the following directions: a b （c）[0 1 2] （d）[1 3 3] （e）[1 1 1] （f）[1 2 2] （g）[1 2 3] （h）[1 0 3] 3.53 Determine the indices for the directions shown in the following cubic unit cell: Direction A: x y z -2/3a b/2